dc.contributor.author | Mears, Kristian L. | |
dc.contributor.author | Nguyen, Gia-Ann | |
dc.contributor.author | Ruiz, Bronson | |
dc.contributor.author | Lehmann, Annika | |
dc.contributor.author | Nelson, Jonah | |
dc.contributor.author | Fettinger, James C. | |
dc.contributor.author | Tuononen, Heikki M. | |
dc.contributor.author | Power, Philip P. | |
dc.date.accessioned | 2024-01-12T09:30:21Z | |
dc.date.available | 2024-01-12T09:30:21Z | |
dc.date.issued | 2024 | |
dc.identifier.citation | Mears, K. L., Nguyen, G.-A., Ruiz, B., Lehmann, A., Nelson, J., Fettinger, J. C., Tuononen, H. M., & Power, P. P. (2024). Hydrobismuthation : Insertion of Unsaturated Hydrocarbons into the Heaviest Main Group Element Bond to Hydrogen. <i>Journal of the American Chemical Society</i>, <i>146</i>(1), 19-23. <a href="https://doi.org/10.1021/jacs.3c06535" target="_blank">https://doi.org/10.1021/jacs.3c06535</a> | |
dc.identifier.other | CONVID_197647025 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/92764 | |
dc.description.abstract | The bismuth hydride (2,6-Mes2H3C6)2BiH (1, Mes = 2,4,6-trimethylphenyl), which has a Bi–H 1H NMR spectroscopic signal at δ = 19.64 ppm, was reacted with phenylacetylene at 60 °C in toluene to yield [(2,6-Mes2C6H3)2BiC(Ph)=CH2] (2) after 15 min. Compound 2 was characterized by 1H, 13C NMR, and UV–vis spectroscopy, single crystal X-ray crystallography, and calculations employing density functional theory. Compound 2 is the first example of a hydrobismuthation addition product and displays Markovnikov regioselectivity. Computational methods indicated that it forms via a radical mechanism with an associated Gibbs energy of activation of 91 kJ mol–1 and a reaction energy of −90 kJ mol–1. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society (ACS) | |
dc.relation.ispartofseries | Journal of the American Chemical Society | |
dc.rights | CC BY-NC-ND 4.0 | |
dc.subject.other | activation energy | |
dc.subject.other | anions | |
dc.subject.other | bismuth | |
dc.subject.other | hydrocarbons | |
dc.subject.other | hydrogen | |
dc.title | Hydrobismuthation : Insertion of Unsaturated Hydrocarbons into the Heaviest Main Group Element Bond to Hydrogen | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202401121265 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 19-23 | |
dc.relation.issn | 0002-7863 | |
dc.relation.numberinseries | 1 | |
dc.relation.volume | 146 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © 2024 the Authors | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 772510 | |
dc.relation.grantnumber | 772510 | |
dc.relation.projectid | info:eu-repo/grantAgreement/EC/H2020/772510/EU//SMAC-MC | |
dc.subject.yso | vety | |
dc.subject.yso | hiilivedyt | |
dc.subject.yso | vismutti | |
dc.subject.yso | anionit | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p16151 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p1169 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p28924 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p27229 | |
dc.rights.url | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.relation.doi | 10.1021/jacs.3c06535 | |
dc.relation.funder | Euroopan komissio | fi |
dc.relation.funder | European Commission | en |
jyx.fundingprogram | ERC Consolidator Grant | fi |
jyx.fundingprogram | ERC Consolidator Grant | en |
jyx.fundinginformation | United States National Science Foundation Grant Nos. CHE-2152760 and CHE-1531193. European Research Council, Horizon 2020 Programme Grant No. 772510. | |
dc.type.okm | A1 | |