Catalytic activity of palladium-based nanostructures in the conversion of simple olefinic hydro- and chlorohydrocarbons from first principles
PublisherUniversity of Jyväskylä
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A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air Kundu, Gourab; Sperger, Theresa; Rissanen, Kari; Schoenebeck, Franziska (Wiley-VCH Verlag, 2020)We report a new air‐stable PdI dimer, [Pd(μ‐I)(PCy2tBu)]2, which triggers E‐selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. ...
Rusanen, Annu; Kupila, Riikka; Lappalainen, Katja; Kärkkäinen, Johanna; Hu, Tao; Lassi, Ulla (MDPI, 2020)In this study, conversion of xylose to furfural was studied using lignin-based activated carbon-supported iron catalysts. First, three activated carbon supports were prepared from hydrolysis lignin with different activation ...
Guven, Sinem; Kundu, Gourab; Weßels, Andrea; Ward, Jas S.; Rissanen, Kari; Schoenebeck, Franziska (American Chemical Society (ACS), 2021)We report a remote functionalization strategy, which allows the Z-selective synthesis of silyl enol ethers of (hetero)aromatic and aliphatic ketones via Ni-catalyzed chain walking from a distant olefin site. The positional ...
Haukka, Matti; Bulatov, Evgeny; Lahtinen, Elmeri; Kivijärvi, Lauri; Hey-Hawkins, Evamarie (Wiley-VCH Verlag, 2020)Selective laser sintering (SLS) 3d printing was utilized to manufacture solid catalyst for Suzuki-Miyaura cross-coupling reactions from polypropylene as a base material and palladium nanoparticles on silica (SilicaCat Pd0 ...
Catalytic Effect of Transition Metals (Copper, Iron, and Nickel) on the Foaming and Properties of Sugar-Based Carbon Foams Varila, Toni; Romar, Henrik; Lassi, Ulla (Springer, 2019)Recently, bio-based carbon foams have gained much interest in many chemical industry felds because of their unique structure and properties. This study provides new information on the efects of catalytic metals (iron, ...