Dioxidomolybdenum(VI) and -tungsten(VI) complexes with tetradentate amino bisphenolates as catalysts for epoxidation
Schachner, J. A., Mösch-Zanetti, N. C., Peuronen, A., & Lehtonen, A. (2017). Dioxidomolybdenum(VI) and -tungsten(VI) complexes with tetradentate amino bisphenolates as catalysts for epoxidation. Polyhedron, 134, 73-78. doi:10.1016/j.poly.2017.06.011
DisciplineEpäorgaaninen ja analyyttinen kemia
© 2017 Elsevier Ltd. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.
Sixteen molybdenum and tungsten complexes with tripodal or linear tetradentate amino bisphenol ligands were studied as catalysts for the epoxidation of cis-cyclooctene, 1-octene, styrene, limonene and α-terpineol. These complexes can be divided into different categories upon key features, i.e. central metal (Mo versus W), side-arm donor (O versus N), hybridization of the N-donor (pyridine versus amine), ligand geometry (tripodal versus linear diamine) and sterical hindrance (Me versus tert-Bu substituents in the phenol part). All complexes can catalyse selectively the epoxidation of cis-cyclooctene by tert-butylhydroperoxide whereas the activities and selectivities towards other olefins (1-octene, styrene, limonene and α-terpineol) show large differences. When H2O2 was used as an oxidant in the epoxidation of cis-cyclooctene, only two of eight Mo complexes and four of eight W complexes showed any activity. This study revealed no clear correlations between the Mo and W catalyst structures and their activities. ...
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Dioxidomolybdenum(VI) and -tungsten(VI) Complexes with Tripodal Amino Bisphenolate Ligands as Epoxidation and Oxo-transfer Catalysts Hossain, Md. Kamal; Schachner, Jörg A.; Haukka, Matti; Lehtonen, Ari; Mösch-Zanetti, Nadia C.; Nordlander, Ebbe (Elsevier Ltd., 2017)The molybdenum(VI) and tungsten(VI) complexes [MO2(L)] (M = Mo (1), W (2), H2L = bis(2-hydroxy-3,5-di-tert-butybenzyl)morpholinylethylamine) were synthesized and the complexes were used to catalyze oxotransfer reactions, ...
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Peuronen, Anssi; Lehtonen, Ari (Springer New York LLC, 2016)Low-cost metallate salts Na2MO4·2H2O (M = molybdenum, tungsten) react with a tridentate amine bisphenol bis(2-hydroxy-3-tert-butyl-5-methylbenzyl)methylamine (H2ONOtBu) under ambient conditions in acidic methanol solutions. ...
Oxidovanadium(V) amine bisphenolates as epoxidation, sulfoxidation and catechol oxidation catalysts Salonen, Pasi; Peuronen, Anssi; Lehtonen, Ari (Elsevier Science, 2017)Air-stable oxidovanadium(V) complexes with tetradentate amine bisphenolate ligands were made by the reaction of VOSO4·xH2O and ligand precursors in MeOH solutions. Isolated compounds were studied as catechol oxidase models ...