Interactions of a Diplumbyne with Dinuclear Transition Metal Carbonyls to Afford Metalloplumbylenes
Zhu, Q., Fettinger, J. C., Vasko, P., & Power, P. P. (2020). Interactions of a Diplumbyne with Dinuclear Transition Metal Carbonyls to Afford Metalloplumbylenes. Organometallics, 39(24), 4629-4636. https://doi.org/10.1021/acs.organomet.0c00659
Julkaistu sarjassa
OrganometallicsPäivämäärä
2020Oppiaine
Epäorgaaninen kemiaEpäorgaaninen ja analyyttinen kemiaInorganic ChemistryInorganic and Analytical ChemistryTekijänoikeudet
© 2020 American Chemical Society
The metathesis reactions of the diplumbyne AriPr6PbPbAriPr6 (AriPr6 = −C6H3–2,6-(C6H2–2,4,6-iPr3)2) with the dinuclear metal carbonyls Mn2(CO)10, Fe2(CO)9, and Co2(CO)8 under mild conditions afforded the complexes Mn(CO)5(PbAriPr6) (1), Fe(CO)4(PbAriPr6)2 (2), and Co4(CO)9(PbAriPr6)2 (3), respectively. Complexes 1–3 were structurally characterized by single-crystal X-ray diffraction and spectroscopically characterized by 1H, 13C{1H}, 59Co{1H}, and 207Pb{1H} NMR; UV–vis; and IR methods. They are rare examples of species formed by the direct reaction of a group 14 dimetallyne with transition metal carbonyls. Complexes 1 and 2 feature Mn–Pb or Fe–Pb single bonds, whereas in 3 a Co–Pb cluster is formed in which the plumbylidyne moiety bridges either an edge or a face of a Co4 carbonyl cluster.
Julkaisija
American Chemical Society (ACS)ISSN Hae Julkaisufoorumista
0276-7333Asiasanat
Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/47317091
Metadata
Näytä kaikki kuvailutiedotKokoelmat
Rahoittaja(t)
Suomen AkatemiaRahoitusohjelmat(t)
Tutkijatohtori, SALisätietoja rahoituksesta
We are grateful to the National Science Foundation (NSF) for financial support (Grant CHE-1565501) and the dual-source X-ray diffractometer (Grant 0840444). P.V. would like to thank the Academy of Finland (project number 314794) and Prof. Heikki M. Tuononen for providing computational resources.Lisenssi
Samankaltainen aineisto
Näytetään aineistoja, joilla on samankaltainen nimeke tai asiasanat.
-
Theoretical and computational studies of magnetic anisotropy and exchange coupling in molecular systems
Mansikkamäki, Akseli (University of Jyväskylä, 2018)The field of molecular magnetism studies the magnetic properties of molecular systems as opposed to conventional metal-based magnets. The high chemical modifiability of the constituting molecules makes such materials highly ... -
Iodination of antipyrine with [N–I–N]+ and carbonyl hypoiodite iodine(i) complexes
Wilson, Laura M. E.; Rissanen, Kari; Ward, Jas S. (Royal Society of Chemistry (RSC), 2023)A series of iodine(I) complexes, both known and new, were synthesised and the dependence of iodination reactivity on the identity of the Lewis bases and anions present was investigated. Using a previously established ... -
Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates
Ward, Jas S.; Martõnova, Jevgenija; Wilson, Laura M. E.; Kramer, Eric; Aav, Riina; Rissanen, Kari (Royal Society of Chemistry (RSC), 2022)The first tris(O–I–N) carbonyl hypoiodites have been synthesised based on trimesic acid and pyridine or 4-methylpyridine, with their structures definitively confirmed by single crystal X-ray diffraction (SCXRD). The more ... -
Thermal expansion and magnetic properties of benzoquinone-bridged dinuclear rare-earth complexes
Moilanen, Jani; Mansikkamäki, Akseli; Lahtinen, Manu; Guo, Fu-Sheng; Kalenius, Elina; Layfield, Richard A.; Chibotaru, Liviu F. (Royal Society of Chemistry, 2017)The synthesis and structural characterization of two benzoquinone-bridged dinuclear rare-earth complexes [BQ(MCl2·THF3)2] (BQ = 2,5-bisoxide-1,4-benzoquinone; M = Y (1), Dy (2)) are described. Of these reported metal ... -
Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong; Tong, Ming-Liang; Mansikkamäki, Akseli; Layfield, Richard A. (American Association for the Advancement of Science, 2018)Single-molecule magnets (SMMs) containing only one metal center may represent the lower size limit for molecule-based magnetic information storage materials. Their current 15 drawback is that all SMMs require liquid-helium ...
Ellei toisin mainittu, julkisesti saatavilla olevia JYX-metatietoja (poislukien tiivistelmät) saa vapaasti uudelleenkäyttää CC0-lisenssillä.