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dc.contributor.authorZhu, Qihao
dc.contributor.authorFettinger, James C.
dc.contributor.authorVasko, Petra
dc.contributor.authorPower, Philip P.
dc.date.accessioned2020-12-15T09:21:34Z
dc.date.available2020-12-15T09:21:34Z
dc.date.issued2020
dc.identifier.citationZhu, Q., Fettinger, J. C., Vasko, P., & Power, P. P. (2020). Interactions of a Diplumbyne with Dinuclear Transition Metal Carbonyls to Afford Metalloplumbylenes. <i>Organometallics</i>, <i>39</i>(24), 4629-4636. <a href="https://doi.org/10.1021/acs.organomet.0c00659" target="_blank">https://doi.org/10.1021/acs.organomet.0c00659</a>
dc.identifier.otherCONVID_47317091
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/73199
dc.description.abstractThe metathesis reactions of the diplumbyne AriPr6PbPbAriPr6 (AriPr6 = −C6H3–2,6-(C6H2–2,4,6-iPr3)2) with the dinuclear metal carbonyls Mn2(CO)10, Fe2(CO)9, and Co2(CO)8 under mild conditions afforded the complexes Mn(CO)5(PbAriPr6) (1), Fe(CO)4(PbAriPr6)2 (2), and Co4(CO)9(PbAriPr6)2 (3), respectively. Complexes 1–3 were structurally characterized by single-crystal X-ray diffraction and spectroscopically characterized by 1H, 13C{1H}, 59Co{1H}, and 207Pb{1H} NMR; UV–vis; and IR methods. They are rare examples of species formed by the direct reaction of a group 14 dimetallyne with transition metal carbonyls. Complexes 1 and 2 feature Mn–Pb or Fe–Pb single bonds, whereas in 3 a Co–Pb cluster is formed in which the plumbylidyne moiety bridges either an edge or a face of a Co4 carbonyl cluster.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherAmerican Chemical Society (ACS)
dc.relation.ispartofseriesOrganometallics
dc.rightsIn Copyright
dc.subject.othermetals
dc.subject.othercarbonyls
dc.subject.othertransition metals
dc.subject.othercobalt
dc.subject.othernuclear magnetic resonance spectroscopy
dc.titleInteractions of a Diplumbyne with Dinuclear Transition Metal Carbonyls to Afford Metalloplumbylenes
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202012157146
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic Chemistryen
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange4629-4636
dc.relation.issn0276-7333
dc.relation.numberinseries24
dc.relation.volume39
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 American Chemical Society
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber314794
dc.subject.ysokarbonyylit
dc.subject.ysoorganometalliyhdisteet
dc.subject.ysokompleksiyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p14898
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1021/acs.organomet.0c00659
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
jyx.fundinginformationWe are grateful to the National Science Foundation (NSF) for financial support (Grant CHE-1565501) and the dual-source X-ray diffractometer (Grant 0840444). P.V. would like to thank the Academy of Finland (project number 314794) and Prof. Heikki M. Tuononen for providing computational resources.


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