Iodination of antipyrine with [N–I–N]+ and carbonyl hypoiodite iodine(i) complexes
Wilson, L. M. E., Rissanen, K., & Ward, J. S. (2023). Iodination of antipyrine with [N–I–N]+ and carbonyl hypoiodite iodine(i) complexes. New Journal of Chemistry, 47(6), 2978-2982. https://doi.org/10.1039/d2nj05349g
Julkaistu sarjassa
New Journal of ChemistryPäivämäärä
2023Tekijänoikeudet
© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2023
A series of iodine(I) complexes, both known and new, were synthesised and the dependence of iodination reactivity on the identity of the Lewis bases and anions present was investigated. Using a previously established screening protocol based on the iodination of antipyrine to iodo-antipyrine, the capability of the iodine(I) species to perform the iodination was tested and compared, especially in relation to Barluenga's reagent, [I(pyridine)2]BF4. The results indicated that the identity of both the Lewis bases and the anion influence the iodination capability of the iodine(I) species, and that the less efficient reagents can deliver favourably comparable percentage conversions with longer reaction times.
Julkaisija
Royal Society of Chemistry (RSC)ISSN Hae Julkaisufoorumista
1144-0546Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/176419109
Metadata
Näytä kaikki kuvailutiedotKokoelmat
Rahoittaja(t)
Suomen AkatemiaRahoitusohjelmat(t)
Akatemiahanke, SA; Akatemiatutkija, SALisätietoja rahoituksesta
The authors gratefully acknowledge the Academy of Finland (K. R. grant no. 351121), the Magnus Ehrnrooth Foundation (J. S. W.), and the University of Jyväskylä, Finland for financial support.Lisenssi
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