Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates
Abstract
The first tris(O–I–N) carbonyl hypoiodites have been synthesised based on trimesic acid and pyridine or 4-methylpyridine, with their structures definitively confirmed by single crystal X-ray diffraction (SCXRD). The more soluble carbonyl hypoiodites based on pivalic acid have also been studied via NMR, SCXRD, and computational analyses, enabling the study of the direct silver(I) precursor and intermediates of the resulting carbonyl hypoiodites generated using a range of substituted pyridines.
Main Authors
Format
Articles
Research article
Published
2022
Series
Subjects
Publication in research information system
Publisher
Royal Society of Chemistry (RSC)
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-202209144593Use this for linking
Review status
Peer reviewed
ISSN
1477-9226
DOI
https://doi.org/10.1039/d2dt01988d
Language
English
Published in
Dalton Transactions
Citation
- Ward, J. S., Martõnova, J., Wilson, L. M. E., Kramer, E., Aav, R., & Rissanen, K. (2022). Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates. Dalton Transactions, 51(38), 14646-14653. https://doi.org/10.1039/d2dt01988d
License
Funder(s)
Research Council of Finland
Funding program(s)
Academy Project, AoF
Akatemiahanke, SA
Additional information about funding
The authors would like to thank the University of Jyväskylä mass spectrometry service for their time and expertise, and gratefully acknowledge the Magnus Ehrnrooth Foundation (J. S. W.), the ERDF DORA travel grant (J. M.), the Estonian Research Council (R.A. grant no. PRG399), the Academy of Finland (K.R. grant no. 317259), and the University of Jyväskylä, Finland for financial support.
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