Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates
Ward, J. S., Martõnova, J., Wilson, L. M. E., Kramer, E., Aav, R., & Rissanen, K. (2022). Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates. Dalton Transactions, 51(38), 14646-14653. https://doi.org/10.1039/d2dt01988d
Julkaistu sarjassa
Dalton TransactionsPäivämäärä
2022Tekijänoikeudet
© The Royal Society of Chemistry 2022
The first tris(O–I–N) carbonyl hypoiodites have been synthesised based on trimesic acid and pyridine or 4-methylpyridine, with their structures definitively confirmed by single crystal X-ray diffraction (SCXRD). The more soluble carbonyl hypoiodites based on pivalic acid have also been studied via NMR, SCXRD, and computational analyses, enabling the study of the direct silver(I) precursor and intermediates of the resulting carbonyl hypoiodites generated using a range of substituted pyridines.
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Royal Society of Chemistry (RSC)ISSN Hae Julkaisufoorumista
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https://converis.jyu.fi/converis/portal/detail/Publication/156485036
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Suomen AkatemiaRahoitusohjelmat(t)
Akatemiahanke, SALisätietoja rahoituksesta
The authors would like to thank the University of Jyväskylä mass spectrometry service for their time and expertise, and gratefully acknowledge the Magnus Ehrnrooth Foundation (J. S. W.), the ERDF DORA travel grant (J. M.), the Estonian Research Council (R.A. grant no. PRG399), the Academy of Finland (K.R. grant no. 317259), and the University of Jyväskylä, Finland for financial support.Lisenssi
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