Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement
Vasko, P., Hurmalainen, J., Mansikkamäki, A., Peuronen, A., Mailman, A., & Tuononen, H. (2017). Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement. Dalton Transactions, 46(46), 16004-16008. https://doi.org/10.1039/c7dt03243a
Julkaistu sarjassa
Dalton TransactionsTekijät
Päivämäärä
2017Oppiaine
Epäorgaaninen ja analyyttinen kemiaNanoscience CenterInorganic and Analytical ChemistryNanoscience CenterTekijänoikeudet
© The Royal Society of Chemistry 2017. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License.
The condensation reaction of 2-aminobenzenethiols and 3-aminopyrazinethiols
with 2-amino-6-fluoro-N-methylpyridinium triflate
afforded thioether derivatives that were found to undergo Smiles
rearrangement and cyclocondensation with sulphur monochloride
to yield new hybrid 1,4-thiazine-1,2,3-dithiazolylium cations. The
synthesized cations were readily reduced to the corresponding
stable neutral radicals with spin densities delocalized over both
1,4-thiazinyl and 1,2,3-dithiazolyl moieties.
Julkaisija
Royal Society of ChemistryISSN Hae Julkaisufoorumista
1477-9226Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/27333692
Metadata
Näytä kaikki kuvailutiedotKokoelmat
Rahoittaja(t)
Suomen Akatemia; Euroopan komissioRahoitusohjelmat(t)
Akatemiahanke, SA; MSCA Marie Skłodowska-Curie Actions, H2020
The content of the publication reflects only the author’s view. The funder is not responsible for any use that may be made of the information it contains.
Lisätietoja rahoituksesta
This work was financially supported by the University of Jyväskylä, the Academy of Finland (projects 253907 and 289172) and the European Union’s H2020 programme (under the Marie Skłodowska-Curie grant agreement 659123). We thank Laboratory Technicians Johanna Lind and Elina Hautakangas for running the +ESI-MS and EA measurements, respectively.Lisenssi
Ellei muuten mainita, aineiston lisenssi on © The Royal Society of Chemistry 2017. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License.
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