Show simple item record

dc.contributor.authorVasko, Petra
dc.contributor.authorHurmalainen, Juha
dc.contributor.authorMansikkamäki, Akseli
dc.contributor.authorPeuronen, Anssi
dc.contributor.authorMailman, Aaron
dc.contributor.authorTuononen, Heikki
dc.date.accessioned2017-12-01T10:06:03Z
dc.date.available2017-12-01T10:06:03Z
dc.date.issued2017
dc.identifier.citationVasko, P., Hurmalainen, J., Mansikkamäki, A., Peuronen, A., Mailman, A., & Tuononen, H. (2017). Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement. <i>Dalton Transactions</i>, <i>46</i>(46), 16004-16008. <a href="https://doi.org/10.1039/c7dt03243a" target="_blank">https://doi.org/10.1039/c7dt03243a</a>
dc.identifier.otherCONVID_27333692
dc.identifier.otherTUTKAID_75596
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/56080
dc.description.abstractThe condensation reaction of 2-aminobenzenethiols and 3-aminopyrazinethiols with 2-amino-6-fluoro-N-methylpyridinium triflate afforded thioether derivatives that were found to undergo Smiles rearrangement and cyclocondensation with sulphur monochloride to yield new hybrid 1,4-thiazine-1,2,3-dithiazolylium cations. The synthesized cations were readily reduced to the corresponding stable neutral radicals with spin densities delocalized over both 1,4-thiazinyl and 1,2,3-dithiazolyl moieties.
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesDalton Transactions
dc.subject.other1,4-thiazinyl-1,2,3-dithiazolyl radicals
dc.subject.otherSmiles rearrangement
dc.titleSynthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201711294424
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-11-29T13:15:15Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange16004-16008
dc.relation.issn1477-9226
dc.relation.numberinseries46
dc.relation.volume46
dc.type.versionpublishedVersion
dc.rights.copyright© The Royal Society of Chemistry 2017. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber289172
dc.relation.grantnumber659123
dc.relation.grantnumber659123
dc.relation.projectidinfo:eu-repo/grantAgreement/EC/H2020/659123/EU//
dc.subject.ysosynteesi
jyx.subject.urihttp://www.yso.fi/onto/yso/p8467
dc.rights.urlhttps://creativecommons.org/licenses/by-nc/3.0/
dc.relation.doi10.1039/c7dt03243a
dc.relation.funderSuomen Akatemiafi
dc.relation.funderEuroopan komissiofi
dc.relation.funderAcademy of Finlanden
dc.relation.funderEuropean Commissionen
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramMSCA Marie Skłodowska-Curie Actions, H2020fi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramMSCA Marie Skłodowska-Curie Actions, H2020en
jyx.fundinginformationThis work was financially supported by the University of Jyväskylä, the Academy of Finland (projects 253907 and 289172) and the European Union’s H2020 programme (under the Marie Skłodowska-Curie grant agreement 659123). We thank Laboratory Technicians Johanna Lind and Elina Hautakangas for running the +ESI-MS and EA measurements, respectively.


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

© The Royal Society of Chemistry 2017. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License.
Except where otherwise noted, this item's license is described as © The Royal Society of Chemistry 2017. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License.