Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct
Hänninen, M. M., Baldansuren, A., & Pugh, T. (2017). Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct. Dalton Transactions, 46(30), 9740-9744. https://doi.org/10.1039/C7DT01226H
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Dalton TransactionsDate
2017Copyright
© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
The solid and solution state structure of the vanadium(II) N‐
heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported
(
SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐
en‐2‐ylidene). The electronic structure of 1 is probed using
combination of magnetic measurements, EPR spectroscopy and
computational studies. The V–Si bond strength and complex
forming mechanism between vanadocene and NHSi ligand is
elucidated using computational methods.
Publisher
Royal Society of ChemistryISSN Search the Publication Forum
1477-9226Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/27013868
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