| dc.contributor.author | Hänninen, Mikko M. | |
| dc.contributor.author | Baldansuren, Amgalanbaatar | |
| dc.contributor.author | Pugh, Thomas | |
| dc.date.accessioned | 2017-08-09T06:40:42Z | |
| dc.date.available | 2018-05-09T21:45:08Z | |
| dc.date.issued | 2017 | |
| dc.identifier.citation | Hänninen, M. M., Baldansuren, A., & Pugh, T. (2017). Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct. <i>Dalton Transactions</i>, <i>46</i>(30), 9740-9744. <a href="https://doi.org/10.1039/C7DT01226H" target="_blank">https://doi.org/10.1039/C7DT01226H</a> | |
| dc.identifier.other | CONVID_27013868 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/55041 | |
| dc.description.abstract | The solid and solution state structure of the vanadium(II) N‐
heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported
(
SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐
en‐2‐ylidene). The electronic structure of 1 is probed using
combination of magnetic measurements, EPR spectroscopy and
computational studies. The V–Si bond strength and complex
forming mechanism between vanadocene and NHSi ligand is
elucidated using computational methods. | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation.ispartofseries | Dalton Transactions | |
| dc.subject.other | kompleksiyhdisteet | |
| dc.subject.other | vanadiini | |
| dc.subject.other | pii | |
| dc.subject.other | coordination complexes | |
| dc.subject.other | vanadium | |
| dc.subject.other | silicon | |
| dc.title | Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201708073424 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2017-08-07T09:15:17Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 9740-9744 | |
| dc.relation.issn | 1477-9226 | |
| dc.relation.numberinseries | 30 | |
| dc.relation.volume | 46 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.subject.yso | kompleksiyhdisteet | |
| dc.subject.yso | vanadiini | |
| dc.subject.yso | pii | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p17151 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p15609 | |
| dc.relation.doi | 10.1039/C7DT01226H | |
| dc.type.okm | A1 | |
