Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct

Hänninen, Mikko M.; Baldansuren, Amgalanbaatar; Pugh, Thomas

doi:10.1039/C7DT01226H

dc.contributor.author	Hänninen, Mikko M.
dc.contributor.author	Baldansuren, Amgalanbaatar
dc.contributor.author	Pugh, Thomas
dc.date.accessioned	2017-08-09T06:40:42Z
dc.date.available	2018-05-09T21:45:08Z
dc.date.issued	2017
dc.identifier.citation	Hänninen, M. M., Baldansuren, A., & Pugh, T. (2017). Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct. <i>Dalton Transactions</i>, <i>46</i>(30), 9740-9744. <a href="https://doi.org/10.1039/C7DT01226H" target="_blank">https://doi.org/10.1039/C7DT01226H</a>
dc.identifier.other	CONVID_27013868
dc.identifier.other	TUTKAID_73838
dc.identifier.uri	https://jyx.jyu.fi/handle/123456789/55041
dc.description.abstract	The solid and solution state structure of the vanadium(II) N‐ heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported ( SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐ en‐2‐ylidene). The electronic structure of 1 is probed using combination of magnetic measurements, EPR spectroscopy and computational studies. The V–Si bond strength and complex forming mechanism between vanadocene and NHSi ligand is elucidated using computational methods.
dc.language.iso	eng
dc.publisher	Royal Society of Chemistry
dc.relation.ispartofseries	Dalton Transactions
dc.subject.other	kompleksiyhdisteet
dc.subject.other	vanadiini
dc.subject.other	pii
dc.subject.other	coordination complexes
dc.subject.other	vanadium
dc.subject.other	silicon
dc.title	Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct
dc.type	article
dc.identifier.urn	URN:NBN:fi:jyu-201708073424
dc.contributor.laitos	Kemian laitos	fi
dc.contributor.laitos	Department of Chemistry	en
dc.contributor.oppiaine	Epäorgaaninen ja analyyttinen kemia	fi
dc.contributor.oppiaine	Inorganic and Analytical Chemistry	en
dc.type.uri	http://purl.org/eprint/type/JournalArticle
dc.date.updated	2017-08-07T09:15:17Z
dc.type.coar	http://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatus	peerReviewed
dc.format.pagerange	9740-9744
dc.relation.issn	1477-9226
dc.relation.numberinseries	30
dc.relation.volume	46
dc.type.version	acceptedVersion
dc.rights.copyright	© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevel	openAccess	fi
dc.subject.yso	kompleksiyhdisteet
dc.subject.yso	vanadiini
dc.subject.yso	pii
jyx.subject.uri	http://www.yso.fi/onto/yso/p30190
jyx.subject.uri	http://www.yso.fi/onto/yso/p17151
jyx.subject.uri	http://www.yso.fi/onto/yso/p15609
dc.relation.doi	10.1039/C7DT01226H
dc.type.okm	A1

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