A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces
Hänninen, M. M., Pal, K., Day, B. M., Pugh, T., & Layfield, R. A. (2016). A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces. Dalton Transactions, 45(28), 11301-11305. https://doi.org/10.1039/C6DT02486F
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Dalton TransactionsDate
2016Copyright
© The Royal Society of Chemistry 2016. This is a final draft version of an article whose final and definitive form has been published by Royal Society if Chemistry. Published in this repository with the kind permission of the publisher.
The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding.
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1477-9226Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/26098574
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Postdoctoral Researcher, AoF