A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces

Hänninen, Mikko M.; Pal, Kuntal; Day, Benjamin M.; Pugh, Thomas; Layfield, Richard A.

doi:10.1039/C6DT02486F

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Hänninen, M. M., Pal, K., Day, B. M., Pugh, T., & Layfield, R. A. (2016). A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces. Dalton Transactions, 45(28), 11301-11305. https://doi.org/10.1039/C6DT02486F

Julkaistu sarjassa

Dalton Transactions

Tekijät

Hänninen, Mikko M. |

Pal, Kuntal |

Day, Benjamin M. |

Pugh, Thomas |

Layfield, Richard A.

Päivämäärä

2016

Oppiaine

Epäorgaaninen ja analyyttinen kemia Inorganic and Analytical Chemistry

Tekijänoikeudet

© The Royal Society of Chemistry 2016. This is a final draft version of an article whose final and definitive form has been published by Royal Society if Chemistry. Published in this repository with the kind permission of the publisher.

The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding.

Julkaisija

RSC Publications

ISSN Hae Julkaisufoorumista

1477-9226

Rahoittaja(t)

Suomen Akatemia

Rahoitusohjelmat(t)

Tutkijatohtori, SA

Lisätietoja rahoituksesta

The authors thank The Academy of Finland (Research Fellowship 274505 to MM) and the EPSRC (EP/K039547/1) for funding.

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