A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces

Hänninen, Mikko M.; Pal, Kuntal; Day, Benjamin M.; Pugh, Thomas; Layfield, Richard A.

doi:10.1039/C6DT02486F

Final Draft

Katso/Avaa

798.9 Kb

Lataukset:

Show download details Hide download details

Hänninen, M. M., Pal, K., Day, B. M., Pugh, T., & Layfield, R. A. (2016). A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces. Dalton Transactions, 45(28), 11301-11305. https://doi.org/10.1039/C6DT02486F

Julkaistu sarjassa

Dalton Transactions

Tekijät

Hänninen, Mikko M. |

Pal, Kuntal |

Day, Benjamin M. |

Pugh, Thomas |

Layfield, Richard A.

Päivämäärä

2016

Oppiaine

Epäorgaaninen ja analyyttinen kemia Inorganic and Analytical Chemistry

Tekijänoikeudet

© The Royal Society of Chemistry 2016. This is a final draft version of an article whose final and definitive form has been published by Royal Society if Chemistry. Published in this repository with the kind permission of the publisher.

The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding.

Julkaisija

RSC Publications

ISSN Hae Julkaisufoorumista

1477-9226

Rahoittaja(t)

Suomen Akatemia

Rahoitusohjelmat(t)

Tutkijatohtori, SA

Lisätietoja rahoituksesta

The authors thank The Academy of Finland (Research Fellowship 274505 to MM) and the EPSRC (EP/K039547/1) for funding.

Näytetään aineistoja, joilla on samankaltainen nimeke tai asiasanat.

Coordination Complexes of a Neutral 1,2,4-Benzotriazinyl Radical Ligand: Synthesis, Molecular and Electronic Structures, and Magnetic Properties

Morgan, Ian; Mansikkamäki, Akseli; Zissimou, Georgia A.; Koutentis, Panayoitis A.; Rouzières, Mathieu; Clérac, Rodolphe; Tuononen, Heikki (Wiley - VCH Verlag GmbH & Co. KGaA, 2015)

A series of d-block metal complexes of the recently reported coordinating neutral radical ligand 1-phenyl-3-(pyrid-2-yl)-1,4-dihydro-1,2,4-benzotriazin-4-yl (1) was synthesized. The investigated systems contain the ...
Side‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel

Puerta Lombardi, Braulio Michele; Gendy, Chris; Gelfand, Benjamin S.; Bernard, Guy M.; Wasylishen, Roderick E.; Tuononen, Heikki M.; Roesler, Roland (Wiley-VCH Verlag, 2021)

A nickel complex incorporating an N2O ligand with a rare η2‐N,N’‐coordination mode was isolated and characterized by X‐ray crystallography, as well as by IR and solid‐state NMR augmented by 15N‐labeling experiments. The ...
Haptotropism in a Nickel Complex with a Neutral, π‐Bridging cyclo‐P4 Ligand Analogous to Cyclobutadiene

Gendy, Chris; Valjus, Juuso; Tuononen, Heikki M.; Roesler, Roland (Wiley-VCH Verlag, 2022)

The reaction of ( 1 )Ni(η 2 -cod), 2 , incorporating a chelating bis( N -heterocyclic carbene) 1 , with P 4 in pentane yielded the dinuclear complex [( 2 )Ni] 2 (μ 2 ,η 2 :η 2 -P 4 ), 3 , formally featuring a cyclobutadiene-like, ...
Nickel as a Lewis Base in a T‐Shaped Nickel(0) Germylene Complex Incorporating a Flexible Bis(NHC) Ligand

Gendy, Chris; Mansikkamäki, Akseli; Valjus, Juuso; Heidebrecht, Joshua; Hui, Paul Chuk-Yan; Bernard, Guy M.; Tuononen, Heikki; Wasylishen, Roderick E.; Michaelis, Vladimir K.; Roesler, Roland (Wiley‐VCH Verlag, 2019)

Flexible, chelating bis(NHC) ligand 2, able to accommodate both cis- and trans-coordination modes, was used to synthesize (2)Ni(η 2 -cod), 3. In reaction with GeCl2, this produced (2)NiGeCl2, 4, featuring a T-shaped Ni(0) ...
Synthesis, X-ray Structure of Two Hexa-Coordinated Ni(II) Complexes with s-Triazine Hydrazine Schiff Base Ligand

Fathalla, Eman M.; Abu-Youssef, Morsy A. M.; Sharaf, Mona M.; El-Faham, Ayman; Barakat, Assem; Haukka, Matti; Soliman, Saied M. (MDPI AG, 2023)

The hydrazine s-triazine ligand (E)-4,4’-(6-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)-1,3,5-triazine-2,4-diyl)dimorpholine (DMPT) was used to synthesize two new Ni(II) complexes via a self-assembly technique. The two ...