Oxidovanadium(v) complexes with l-proline-based amino acid phenolates
Salonen, P., Peuronen, A., Sinkkonen, J., & Lehtonen, A. (2019). Oxidovanadium(v) complexes with l-proline-based amino acid phenolates. Inorganica Chimica Acta, 489, 108-114. https://doi.org/10.1016/j.ica.2019.02.011
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Inorganica Chimica ActaDate
2019Copyright
© 2019 Elsevier B.V.
L-proline was used to prepare chiral, tridentate amino acid phenol proligands H2L1—4. These
proligands react with vanadium precursors VO(acac)2, VOSO4 ∙ 5 H2O and VO(OPr)3 in
methanol to form the corresponding oxidoalkoxidovanadium(V) complexes 1—4. The
complexes crystallize from methanol, and are octahedrally coordinated with a general
formula [VO(L1—4)(OMe)(MeOH)]. In solution, however, they adopt several different
conformations or isomeric structures depending on the solvent.
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Elsevier BVISSN Search the Publication Forum
0020-1693Keywords
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