dc.contributor.author | Tomyn, Stefania | |
dc.contributor.author | Haukka, Matti | |
dc.contributor.author | Nedelkov, Ruslan | |
dc.date.accessioned | 2016-02-09T07:08:20Z | |
dc.date.available | 2016-02-09T07:08:20Z | |
dc.date.issued | 2012 | |
dc.identifier.citation | Tomyn, S., Haukka, M., & Nedelkov, R. (2012). Diammine{N-[2-(hydroxyimino)propionyl]-N'-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ4 N,N',N'',N'''}iron(III). <i>Acta Crystallographica Section E</i>, <i>E68</i>(12), m1568-m1569. <a href="https://doi.org/10.1107/S160053681204826X" target="_blank">https://doi.org/10.1107/S160053681204826X</a> | |
dc.identifier.other | CONVID_22114377 | |
dc.identifier.other | TUTKAID_54095 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/48687 | |
dc.description.abstract | In the title compound, [Fe(C9H13N4O4)(NH3)2], the FeIII
atom, lying on a mirror plane, is coordinated by four N atoms
of a triply deprotonated tetradentate N-[2-(hydroxyimino)-
propionyl]-N0
-[2-(oxidoimino)propionyl]propane-1,3-diaminide
ligand in the equatorial plane and two N atoms of two
ammonia molecules at the axial positions in a distorted
octahedral geometry. A short intramolecular O—HO
hydrogen bond between the cis-disposed oxime O atoms
stabilizes the pseudo-macrocyclic configuration of the ligand.
In the crystal, molecules are linked by N—HO hydrogen
bonds into a three-dimensional network. The ligand has a
mirror-plane symmetry. One of the methylene groups of the
propane bridge is disordered over two sets of sites with equal
occupancy factors. | |
dc.language.iso | eng | |
dc.publisher | Wiley-Blackwell | |
dc.relation.ispartofseries | Acta Crystallographica Section E | |
dc.relation.uri | http://journals.iucr.org/e/journalhomepage.html | |
dc.subject.other | single-crystal X-ray study | |
dc.subject.other | disorder in main residue | |
dc.title | Diammine{N-[2-(hydroxyimino)propionyl]-N'-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ4 N,N',N'',N'''}iron(III) | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201602041443 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Kemia | fi |
dc.contributor.oppiaine | Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2016-02-04T10:15:20Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | m1568-m1569 | |
dc.relation.issn | 1600-5368 | |
dc.relation.numberinseries | 12 | |
dc.relation.volume | E68 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence. | |
dc.rights.accesslevel | openAccess | fi |
dc.rights.url | http://creativecommons.org/licenses/by/2.0/uk/legalcode | |
dc.relation.doi | 10.1107/S160053681204826X | |
dc.type.okm | A1 | |