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cis-Dichloridobis(2-isocyanophenyl 4-methoxybenzoate)palladium(II) chloroform monosolvate

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Tskhovrebov, A., & Haukka, M. (2012). cis-Dichloridobis(2-isocyanophenyl 4-methoxybenzoate)palladium(II) chloroform monosolvate. Acta Crystallographica Section E, E68(12), m1476-m1477. https://doi.org/10.1107/S1600536812045801
Published in
Acta Crystallographica Section E
Authors
Tskhovrebov, Alexander |
Haukka, Matti
Date
2012
Discipline
Epäorgaaninen ja analyyttinen kemiaInorganic and Analytical Chemistry
Copyright
Copyright © International Union of Crystallography

 
In the title compound, [PdCl2(C15H11NO3)2]·CHCl3, the PdII atom adopts a slightly distorted square-planar coordination geometry composed of two Cl atoms in cis positions and two C atoms from isocyano­phenyl ligands. The mol­ecular conformation is stabilized by [pi]-[pi] stacking inter­actions [shortest centroid-centroid distance = 3.600 (1) Å] between substituted benzene rings of different ligands. The crystal packing is characterized by C-H...O and C-H...Cl inter­actions involving the chloro­form solvent mol­ecules.
Publisher
Wiley-Blackwell
ISSN Search the Publication Forum
1600-5368
Keywords
single-crystal X-ray study molecular conformation crystal packing chloroform solvent molecules

Original source
http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1600-5368

DOI
https://doi.org/10.1107/S1600536812045801
URI

http://urn.fi/URN:NBN:fi:jyu-201603101805

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/22113658

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  • Matemaattis-luonnontieteellinen tiedekunta [4944]

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