4,4-Difluoro-2,3;5,6-bis(tetramethylene)-4-bora-3a,4a-diaza-s-indacene (LD540)
Abstract
The title compound, C18H21BF2N2, is a lipophilic dye based on
a BODIPY fluorophore backbone, which was developed for
microscopic imaging of lipid droplets; the molecule has a
planar BODIPY core [dihedral angle between the pyrrole
rings = 2.3 (3)] and two tetramethylene substituents at the
2,3- and 5,6-positions in a half-chair conformation. One of the
tetramethylene substituents is disordered over two two sets of
sites with site occupancies of 0.5. In the crystal, pairs of C—
HF interactions link the molecules into inversion dimers.
Neighbouring dimers are linked by further C—HF interactions,
forming an infinite array. C—H and –
[centroid–centroid distance = 4.360 (3) A˚ ] interactions are
observed between the BODIPY core and the tetramethylene
substituents of neighbouring dimer pairs.
Main Authors
Format
Articles
Research article
Published
2014
Series
Subjects
Publication in research information system
Publisher
IUCr
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201602011360Käytä tätä linkitykseen.
Review status
Peer reviewed
ISSN
1600-5368
DOI
https://doi.org/10.1107/S1600536813033448
Language
English
Published in
Acta Crystallographica Section E : Structure Reports Online
Citation
- Salorinne, K., Tero, T.-R., & Lahtinen, T. (2014). 4,4-Difluoro-2,3;5,6-bis(tetramethylene)-4-bora-3a,4a-diaza-s-indacene (LD540). Acta Crystallographica Section E : Structure Reports Online, 70(1), o74. https://doi.org/10.1107/S1600536813033448
Copyright© the Authors, 2014. This is an open access article published by IUCr.