4,4-Difluoro-2,3;5,6-bis(tetramethylene)-4-bora-3a,4a-diaza-s-indacene (LD540)

Abstract
The title compound, C18H21BF2N2, is a lipophilic dye based on a BODIPY fluorophore backbone, which was developed for microscopic imaging of lipid droplets; the molecule has a planar BODIPY core [dihedral angle between the pyrrole rings = 2.3 (3)] and two tetramethylene substituents at the 2,3- and 5,6-positions in a half-chair conformation. One of the tetramethylene substituents is disordered over two two sets of sites with site occupancies of 0.5. In the crystal, pairs of C— HF interactions link the molecules into inversion dimers. Neighbouring dimers are linked by further C—HF interactions, forming an infinite array. C—H and – [centroid–centroid distance = 4.360 (3) A˚ ] interactions are observed between the BODIPY core and the tetramethylene substituents of neighbouring dimer pairs.
Main Authors
Format
Articles Research article
Published
2014
Series
Subjects
Publication in research information system
Publisher
IUCr
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201602011360Käytä tätä linkitykseen.
Review status
Peer reviewed
ISSN
1600-5368
DOI
https://doi.org/10.1107/S1600536813033448
Language
English
Published in
Acta Crystallographica Section E : Structure Reports Online
Citation
  • Salorinne, K., Tero, T.-R., & Lahtinen, T. (2014). 4,4-Difluoro-2,3;5,6-bis(tetramethylene)-4-bora-3a,4a-diaza-s-indacene (LD540). Acta Crystallographica Section E : Structure Reports Online, 70(1), o74. https://doi.org/10.1107/S1600536813033448
License
Open Access
Copyright© the Authors, 2014. This is an open access article published by IUCr.

Share