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4,4-Difluoro-2,3;5,6-bis(tetramethylene)-4-bora-3a,4a-diaza-s-indacene (LD540)

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Salorinne, K., Tero, T.-R., & Lahtinen, T. (2014). 4,4-Difluoro-2,3;5,6-bis(tetramethylene)-4-bora-3a,4a-diaza-s-indacene (LD540). Acta Crystallographica Section E : Structure Reports Online, 70(1), o74. https://doi.org/10.1107/S1600536813033448
Published in
Acta Crystallographica Section E : Structure Reports Online
Authors
Salorinne, Kirsi |
Tero, Tiia-Riikka |
Lahtinen, Tanja
Date
2014
Discipline
Fysikaalinen kemiaOrgaaninen kemiaNanoscience CenterPhysical ChemistryOrganic ChemistryNanoscience Center
Copyright
© the Authors, 2014. This is an open access article published by IUCr.

 
The title compound, C18H21BF2N2, is a lipophilic dye based on a BODIPY fluorophore backbone, which was developed for microscopic imaging of lipid droplets; the molecule has a planar BODIPY core [dihedral angle between the pyrrole rings = 2.3 (3)] and two tetramethylene substituents at the 2,3- and 5,6-positions in a half-chair conformation. One of the tetramethylene substituents is disordered over two two sets of sites with site occupancies of 0.5. In the crystal, pairs of C— HF interactions link the molecules into inversion dimers. Neighbouring dimers are linked by further C—HF interactions, forming an infinite array. C—H and – [centroid–centroid distance = 4.360 (3) A˚ ] interactions are observed between the BODIPY core and the tetramethylene substituents of neighbouring dimer pairs.
Publisher
IUCr
ISSN Search the Publication Forum
1600-5368
Keywords
LD540 BODIPY lipofiilinen väriaine yksikideröntgendiffraktiotutkimus BODIBY lipophilic dye single-crystal X-ray study
DOI
https://doi.org/10.1107/S1600536813033448
URI

http://urn.fi/URN:NBN:fi:jyu-201602011360

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/22940490

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