Diammine{N-[2-(hydroxyimino)propionyl]-N'-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ4 N,N',N'',N'''}iron(III)
Tomyn, S., Haukka, M., & Nedelkov, R. (2012). Diammine{N-[2-(hydroxyimino)propionyl]-N'-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ4 N,N',N'',N'''}iron(III). Acta Crystallographica Section E, E68(12), m1568-m1569. https://doi.org/10.1107/S160053681204826X
Julkaistu sarjassa
Acta Crystallographica Section EPäivämäärä
2012Tekijänoikeudet
© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
In the title compound, [Fe(C9H13N4O4)(NH3)2], the FeIII
atom, lying on a mirror plane, is coordinated by four N atoms
of a triply deprotonated tetradentate N-[2-(hydroxyimino)-
propionyl]-N0
-[2-(oxidoimino)propionyl]propane-1,3-diaminide
ligand in the equatorial plane and two N atoms of two
ammonia molecules at the axial positions in a distorted
octahedral geometry. A short intramolecular O—HO
hydrogen bond between the cis-disposed oxime O atoms
stabilizes the pseudo-macrocyclic configuration of the ligand.
In the crystal, molecules are linked by N—HO hydrogen
bonds into a three-dimensional network. The ligand has a
mirror-plane symmetry. One of the methylene groups of the
propane bridge is disordered over two sets of sites with equal
occupancy factors.
Julkaisija
Wiley-BlackwellISSN Hae Julkaisufoorumista
1600-5368
Alkuperäislähde
http://journals.iucr.org/e/journalhomepage.htmlJulkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/22114377
Metadata
Näytä kaikki kuvailutiedotKokoelmat
Lisenssi
Ellei muuten mainita, aineiston lisenssi on © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
Samankaltainen aineisto
Näytetään aineistoja, joilla on samankaltainen nimeke tai asiasanat.
-
2-(3,5-Dimethyl-1H-pyrazol-1-yl)-2-hydroxyimino-N0-[1-(pyridin-2-yl)ethylethylidene]
Plutenko, Maxym O.; Lampeka, Rostislav D.; Haukka, Matti; Nordlander, Ebbe (Wiley-Blackwell, 2012)In the title compound, C14H16N6O2, the dihedral angles formed by the mean plane of the acetohydrazide group [maximum deviation 0.0629 (12) A˚ ] with the pyrazole and pyridine rings are 81.62 (6) and 38.38 (4) respectively. ... -
4-Methyl/Phenyl-1,2,5,6-tetraazafluoranthen-3(2H)-ones Synthesis : Mechanistic Pathway Study and Single-Crystal X-ray Analysis of the Intermediates
Sarhan, Ahmed A. M.; Haukka, Matti; Barakat, Assem; Soliman, Saied M.; Boraei, Ahmed T. A.; Sopaih, Manar; Salama, Eid E. (MDPI, 2023)The synthesis of 4-methyl/phenyl-1,2,5,6-tetraazafluoranthen-3(2H)-one 4 and 7 has been reported with ninhydrin via a reaction first with ethyl acetoacetate or ethyl benzoylacetate and then a reaction of the resultant ... -
A second monoclinic polymorph of 2-(3,5-dimethyl-1H-pyrazol-1-yl)-2-hydroxyimino-N'-[1-(pyridin-2-yl)ethylidene]acetohydrazide
Plutenko, M. O.; Lampeka, R. D.; Haukka, Matti; Nordlander, E. (Wiley-Blackwell Publishing, Inc., 2013)[Introduction] The title compound, C 14 H 16 N 6 O 2 , is a second monoclinic polymorph of 2-[1-(3,5-dimethyl)pyrazolyl]-2-hydroxyimino- N 0 -[1-(2-pyridyl)ethylidene] acetohydrazide, with two crystal- lographically ... -
6-Amino-2-(pivaloylamino)pyridinium benzoate
Checinska, Lilianna; Osmialowski, Borys; Valkonen, Arto (International Union of Crystallography, 2013)In the crystal structure of the title salt, C₁₀H₁₆N₃O⁺·C₇H₅O₂ˉ, the cations and anions are linked to each other via N-H...O hydrogen bonds, forming infinite chains running along [010]. The crystal structure also features ... -
4,4-Difluoro-2,3;5,6-bis(tetramethylene)-4-bora-3a,4a-diaza-s-indacene (LD540)
Salorinne, Kirsi; Tero, Tiia-Riikka; Lahtinen, Tanja (IUCr, 2014)The title compound, C18H21BF2N2, is a lipophilic dye based on a BODIPY fluorophore backbone, which was developed for microscopic imaging of lipid droplets; the molecule has a planar BODIPY core [dihedral angle between ...
Ellei toisin mainittu, julkisesti saatavilla olevia JYX-metatietoja (poislukien tiivistelmät) saa vapaasti uudelleenkäyttää CC0-lisenssillä.