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dc.contributor.authorRekken, Brian
dc.contributor.authorBrown, Thomas
dc.contributor.authorFettinger, James
dc.contributor.authorTuononen, Heikki
dc.contributor.authorPower, Philip
dc.date.accessioned2015-11-24T07:41:12Z
dc.date.available2015-11-24T07:41:12Z
dc.date.issued2012
dc.identifier.citationRekken, B., Brown, T., Fettinger, J., Tuononen, H., & Power, P. (2012). Isolation of a Stable, Acyclic, Two-Coordinate Silylene. <em>Journal of the American Chemical Society</em>, 134 (15), 6504-6507. <a href="http://dx.doi.org/10.1021/ja301091v">doi:10.1021/ja301091v</a>
dc.identifier.otherTUTKAID_51468
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47795
dc.description.abstractThe synthesis and characterization of a stable, acyclic two-coordinate silylene, Si(SArMe6)2, (ArMe6 = C6H3-2,6(C6H2-2,4,6-Me3)2) by reduction of Br2Si(SArMe6)2 with a magnesium(I) reductant is described. It features a v-shaped silicon coordination with a S-Si-S angle of 90.519(2)° and an average Si-S distance of 2.158(3) Å. Although it reacts readily with an alkyl halide, it does not react with hydrogen under ambient conditions probably as a result of the ca. 4.3 eV energy difference between the frontier silicon lone pair and 3p orbitals.
dc.language.isoeng
dc.publisherACS
dc.relation.ispartofseriesJournal of the American Chemical Society
dc.subject.otherpysyvät silyleenit
dc.subject.otherstable silylenes
dc.titleIsolation of a Stable, Acyclic, Two-Coordinate Silylene
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201511243779
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-11-24T07:15:24Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange6504-6507
dc.relation.issn0002-7863
dc.relation.volume134
dc.type.versionacceptedVersion
dc.rights.copyright© 2012 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1021/ja301091v


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