Paramagnetic aluminium β-diketiminate
Moilanen, J., Borau-Garcia, J., Roesler, R., & Tuononen, H. (2012). Paramagnetic aluminium β-diketiminate. Chemical Communications, 48 (71), 8949-8951. doi:10.1039/C2CC34051H
Published inChemical Communications
DisciplineEpäorgaaninen ja analyyttinen kemia
© The Royal Society of Chemistry 2012. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic complex was characterized by EPR spectroscopy and computational chemistry.