| dc.contributor.author | Rekken, Brian | |
| dc.contributor.author | Brown, Thomas | |
| dc.contributor.author | Fettinger, James | |
| dc.contributor.author | Tuononen, Heikki | |
| dc.contributor.author | Power, Philip | |
| dc.date.accessioned | 2015-11-24T07:41:12Z | |
| dc.date.available | 2015-11-24T07:41:12Z | |
| dc.date.issued | 2012 | |
| dc.identifier.citation | Rekken, B., Brown, T., Fettinger, J., Tuononen, H., & Power, P. (2012). Isolation of a Stable, Acyclic, Two-Coordinate Silylene. <i>Journal of the American Chemical Society</i>, <i>134</i>(15), 6504-6507. <a href="https://doi.org/10.1021/ja301091v" target="_blank">https://doi.org/10.1021/ja301091v</a> | |
| dc.identifier.other | CONVID_21544960 | |
| dc.identifier.other | TUTKAID_51468 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47795 | |
| dc.description.abstract | The synthesis and characterization of a
stable, acyclic two-coordinate silylene, Si(SArMe6)2,
(ArMe6 = C6H3-2,6(C6H2-2,4,6-Me3)2) by reduction of
Br2Si(SArMe6)2 with a magnesium(I) reductant is described.
It features a v-shaped silicon coordination
with a S-Si-S angle of 90.519(2)° and an average Si-S
distance of 2.158(3) Å. Although it reacts readily with
an alkyl halide, it does not react with hydrogen under
ambient conditions probably as a result of the ca. 4.3
eV energy difference between the frontier silicon lone
pair and 3p orbitals. | |
| dc.language.iso | eng | |
| dc.publisher | ACS | |
| dc.relation.ispartofseries | Journal of the American Chemical Society | |
| dc.subject.other | pysyvät silyleenit | |
| dc.subject.other | stable silylenes | |
| dc.title | Isolation of a Stable, Acyclic, Two-Coordinate Silylene | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201511243779 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2015-11-24T07:15:24Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 6504-6507 | |
| dc.relation.issn | 0002-7863 | |
| dc.relation.numberinseries | 15 | |
| dc.relation.volume | 134 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2012 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.doi | 10.1021/ja301091v | |
| dc.type.okm | A1 | |
