Stable spirocyclic neutral radicals: aluminum and gallium boraamidinates
Abstract
Stable dark red (M = Al) or dark green (M = Ga) neutral radicals {[PhB(μ-NtBu)2]2M}˙ are obtained by the oxidation of their corresponding anions with iodine, and EPR spectra supported by DFT calculations show that the spin density is equally delocalized over all four nitrogen atoms in these spiroconjugated systems.
Main Authors
Format
Articles
Research article
Published
2005
Series
Subjects
Publication in research information system
Publisher
RSC
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201511183694Use this for linking
Review status
Peer reviewed
ISSN
1359-7345
DOI
https://doi.org/10.1039/B506253E
Language
English
Published in
Chemical Communications
Citation
- Chivers, T., Eisler, D., Fedorchuk, C., Schatte, G., Tuononen, H., & Boeré, R. (2005). Stable spirocyclic neutral radicals: aluminum and gallium boraamidinates. Chemical Communications, (31), 3930-3932. https://doi.org/10.1039/B506253E
License
Copyright© The Royal Society of Chemistry 2005. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.