Synthesis, crystal structure, and gas sorption studies of two neutral octahedral {MII24}-cages built from sulfonylcalix[4]arene tetranuclear clusters and triazine linkers

Khariushin, Ivan V.; Bulach, Véronique; Ward, Jas S.; Rissanen, Kari; Solovieva, Svetlana E.; Antipin, Igor S.; Ovsyannikov, Alexander S.; Ferlay, Sylvie

doi:10.1039/d4ce00964a

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Khariushin, I. V., Bulach, V., Ward, J. S., Rissanen, K., Solovieva, S. E., Antipin, I. S., Ovsyannikov, A. S., & Ferlay, S. (2024). Synthesis, crystal structure, and gas sorption studies of two neutral octahedral {MII24}-cages built from sulfonylcalix[4]arene tetranuclear clusters and triazine linkers. CrystEngComm, 26(48), 6789-6795. https://doi.org/10.1039/d4ce00964a

Julkaistu sarjassa

CrystEngComm

Tekijät

Khariushin, Ivan V. |

Bulach, Véronique |

Ward, Jas S. |

Rissanen, Kari |

Solovieva, Svetlana E. |

Antipin, Igor S. |

Ovsyannikov, Alexander S. |

Ferlay, Sylvie

Päivämäärä

2024

Pääsyrajoitukset

Embargo päättyy: 2025-11-07Pyydä artikkeli tutkijalta

Tekijänoikeudet

Two isostructural nanosized coordination cages of formula [MII4SO2TCA(μ4-OH2)]6TATB8·nS (M = Co or Ni, SO2TCA = sulfonylcalix[4]arene, TATB = 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoate trisanion, S are solvent molecules) were obtained following a three-components strategy, using two different synthetic methods, leading to face-panelled octahedral coordination cages. The compounds were thoroughly analysed from a structural point of view, and for M = Co, the adsorption properties were measured, revealing a high surface area (SA = 742 m2 g−1) and a large CO2 uptake for these types of compounds.

Julkaisija

Royal Society of Chemistry

ISSN Hae Julkaisufoorumista

1466-8033

Lisätietoja rahoituksesta

This work was supported by the University of Strasbourg, Fondation Jean-Marie Lehn, the University of Jyväskylä, a Doctoral Verdnaskii scholarship from French Embassy (I. V. K.), the Centre National de la Recherche Scientifique (France) and the Russian Science Foundation (Project No. 19-73-20035 to A. S. O., S. E. S., I. S. A.).

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