Synthesis, crystal structure, and gas sorption studies of two neutral octahedral {MII24}-cages built from sulfonylcalix[4]arene tetranuclear clusters and triazine linkers
| dc.contributor.author | Khariushin, Ivan V. | |
| dc.contributor.author | Bulach, Véronique | |
| dc.contributor.author | Ward, Jas S. | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Solovieva, Svetlana E. | |
| dc.contributor.author | Antipin, Igor S. | |
| dc.contributor.author | Ovsyannikov, Alexander S. | |
| dc.contributor.author | Ferlay, Sylvie | |
| dc.date.accessioned | 2024-12-19T06:16:37Z | |
| dc.date.available | 2024-12-19T06:16:37Z | |
| dc.date.issued | 2024 | |
| dc.identifier.citation | Khariushin, I. V., Bulach, V., Ward, J. S., Rissanen, K., Solovieva, S. E., Antipin, I. S., Ovsyannikov, A. S., & Ferlay, S. (2024). Synthesis, crystal structure, and gas sorption studies of two neutral octahedral {MII24}-cages built from sulfonylcalix[4]arene tetranuclear clusters and triazine linkers. <i>CrystEngComm</i>, <i>26</i>(48), 6789-6795. <a href="https://doi.org/10.1039/d4ce00964a" target="_blank">https://doi.org/10.1039/d4ce00964a</a> | |
| dc.identifier.other | CONVID_244282577 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/99065 | |
| dc.description.abstract | Two isostructural nanosized coordination cages of formula [MII4SO2TCA(μ4-OH2)]6TATB8·nS (M = Co or Ni, SO2TCA = sulfonylcalix[4]arene, TATB = 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoate trisanion, S are solvent molecules) were obtained following a three-components strategy, using two different synthetic methods, leading to face-panelled octahedral coordination cages. The compounds were thoroughly analysed from a structural point of view, and for M = Co, the adsorption properties were measured, revealing a high surface area (SA = 742 m2 g−1) and a large CO2 uptake for these types of compounds. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation.ispartofseries | CrystEngComm | |
| dc.rights | In Copyright | |
| dc.title | Synthesis, crystal structure, and gas sorption studies of two neutral octahedral {MII24}-cages built from sulfonylcalix[4]arene tetranuclear clusters and triazine linkers | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202412197876 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 6789-6795 | |
| dc.relation.issn | 1466-8033 | |
| dc.relation.numberinseries | 48 | |
| dc.relation.volume | 26 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © The Royal Society of Chemistry 2024 | |
| dc.rights.accesslevel | embargoedAccess | fi |
| dc.type.publication | article | |
| dc.subject.yso | organometalliyhdisteet | |
| dc.subject.yso | kompleksiyhdisteet | |
| dc.subject.yso | kemiallinen synteesi | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p28123 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8468 | |
| dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
| dc.relation.doi | 10.1039/d4ce00964a | |
| jyx.fundinginformation | This work was supported by the University of Strasbourg, Fondation Jean-Marie Lehn, the University of Jyväskylä, a Doctoral Verdnaskii scholarship from French Embassy (I. V. K.), the Centre National de la Recherche Scientifique (France) and the Russian Science Foundation (Project No. 19-73-20035 to A. S. O., S. E. S., I. S. A.). | |
| dc.type.okm | A1 |
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