Mono- and Bis-Carbonyl Hypoiodites of the Tertiary Amines Quinuclidine and DABCO
| dc.contributor.author | Yu, Shilin | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Ward, Jas S. | |
| dc.date.accessioned | 2024-06-12T09:43:25Z | |
| dc.date.available | 2024-06-12T09:43:25Z | |
| dc.date.issued | 2024 | |
| dc.identifier.citation | Yu, S., Rissanen, K., & Ward, J. S. (2024). Mono- and Bis-Carbonyl Hypoiodites of the Tertiary Amines Quinuclidine and DABCO. <i>Crystal Growth and Design</i>, <i>Early online</i>. <a href="https://doi.org/10.1021/acs.cgd.4c00377" target="_blank">https://doi.org/10.1021/acs.cgd.4c00377</a> | |
| dc.identifier.other | CONVID_220343493 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/95802 | |
| dc.description.abstract | Mono- and bis-carbonyl hypoiodites incorporating the tertiary amines quinuclidine (1a–e) or 1,4-diazabicyclo[2.2.2]octane (DABCO; 2a, 2b, and 2e), respectively, have been synthesized and represent the first examples of hypoiodites stabilized by alkyl amines rather than aromatic Lewis bases (e.g., pyridine derivatives). These highly reactive complexes have been characterized in the solid state by SCXRD and DFT calculations. The DABCO hypoiodite derivatives are rare examples of ditopic bis(O–I–N) complexes and were found to display unexpected bonding parameters relative to iodine(I) complexes in which the DABCO is coordinating in a monotopic manner. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society (ACS) | |
| dc.relation.ispartofseries | Crystal Growth and Design | |
| dc.rights | CC BY-NC-ND 4.0 | |
| dc.subject.other | amines | |
| dc.subject.other | carbonyls | |
| dc.subject.other | chemical structure | |
| dc.subject.other | Lewis bases | |
| dc.subject.other | ligands | |
| dc.title | Mono- and Bis-Carbonyl Hypoiodites of the Tertiary Amines Quinuclidine and DABCO | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202406124569 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.relation.issn | 1528-7483 | |
| dc.relation.volume | Early online | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2024 the Authors | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.grantnumber | 351121 | |
| dc.relation.grantnumber | 356187 | |
| dc.subject.yso | amiinit | |
| dc.subject.yso | ligandit | |
| dc.subject.yso | karbonyylit | |
| dc.subject.yso | kemiallinen koostumus | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p9219 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p24741 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p14898 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p19431 | |
| dc.rights.url | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
| dc.relation.doi | 10.1021/acs.cgd.4c00377 | |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Suomen Akatemia | fi |
| dc.relation.funder | Suomen Akatemia | fi |
| jyx.fundingprogram | Academy Project, AoF | en |
| jyx.fundingprogram | Academy Research Fellow, AoF | en |
| jyx.fundingprogram | Akatemiahanke, SA | fi |
| jyx.fundingprogram | Akatemiatutkija, SA | fi |
| jyx.fundinginformation | The authors gratefully acknowledge the Academy of Finland (J.S.W. grant no. 356187; K.R. grant no. 351121) and the University of Jyväskylä, Finland, for financial support. | |
| dc.type.okm | A1 |
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