Mono- and Bis-Carbonyl Hypoiodites of the Tertiary Amines Quinuclidine and DABCO
Yu, S., Rissanen, K., & Ward, J. S. (2024). Mono- and Bis-Carbonyl Hypoiodites of the Tertiary Amines Quinuclidine and DABCO. Crystal Growth and Design, Early online. https://doi.org/10.1021/acs.cgd.4c00377
Julkaistu sarjassa
Crystal Growth and DesignPäivämäärä
2024Tekijänoikeudet
© 2024 the Authors
Mono- and bis-carbonyl hypoiodites incorporating the tertiary amines quinuclidine (1a–e) or 1,4-diazabicyclo[2.2.2]octane (DABCO; 2a, 2b, and 2e), respectively, have been synthesized and represent the first examples of hypoiodites stabilized by alkyl amines rather than aromatic Lewis bases (e.g., pyridine derivatives). These highly reactive complexes have been characterized in the solid state by SCXRD and DFT calculations. The DABCO hypoiodite derivatives are rare examples of ditopic bis(O–I–N) complexes and were found to display unexpected bonding parameters relative to iodine(I) complexes in which the DABCO is coordinating in a monotopic manner.
Julkaisija
American Chemical Society (ACS)ISSN Hae Julkaisufoorumista
1528-7483Asiasanat
Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/220343493
Metadata
Näytä kaikki kuvailutiedotKokoelmat
Rahoittaja(t)
Suomen AkatemiaRahoitusohjelmat(t)
Akatemiahanke, SA; Akatemiatutkija, SALisätietoja rahoituksesta
The authors gratefully acknowledge the Academy of Finland (J.S.W. grant no. 356187; K.R. grant no. 351121) and the University of Jyväskylä, Finland, for financial support.Lisenssi
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