Solid‐state NMR Spectroscopy of Iodine(I) Complexes
Ward, J. S., Sievänen, E. I., & Rissanen, K. (2023). Solid‐state NMR Spectroscopy of Iodine(I) Complexes. Chemistry : An Asian Journal, 18(6), Article e202201203. https://doi.org/10.1002/asia.202201203
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Chemistry : An Asian JournalDate
2023Copyright
© 2023 Wiley-VCH GmbH
Solid-state NMR has been applied to a series of Barluenga-type iodine(I) [L-I-L]PF6 (L=pyridine, 4-ethylpyridine, 4-dimethylaminopyridine, isoquinoline) complexes as their hexafluorophosphate salts, as well as their respective non-liquid ligands (L), their precursor silver(I) complexes, and the respective N-methylated pyridinium and quinolinium hexafluorophoshate salts. These results are compared and contrasted to the corresponding solution studies and single-crystal X-ray structures. As the first study of its kind on the solid-state NMR behavior of halogen(I) complexes, practical considerations are also discussed to encourage wider utilization of this technique in the future.
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Wiley-VCH VerlagISSN Search the Publication Forum
1861-4728Keywords
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https://converis.jyu.fi/converis/portal/detail/Publication/176801416
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Research Council of FinlandFunding program(s)
Academy Project, AoF; Academy Research Fellow, AoFAdditional information about funding
Academy of Finland (K.R. grant no. 351121)License
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