The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6
Ward, J. S. (2022). The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6. CrystEngComm, 24(40), 7029-7033. https://doi.org/10.1039/d2ce01225a
© The Royal Society of Chemistry 2022
The first iodine(I) complex bearing hydrogen-bond donor and acceptor groups, [bis(3-acetaminopyridine)iodine(I)]PF6 (3), was synthesised, which exhibited two temperature-dependent solid-state connectivities of the hydrogen bonding. Upon reaction of 3 with tBuOMe, unprecedented iodination of a tBu methyl group proceeded under exceptionally mild conditions in good yield.
PublisherRoyal Society of Chemistry (RSC)
Publication in research information system
MetadataShow full item record
Related funder(s)Academy of Finland
Funding program(s)Academy Research Fellow, AoF
Additional information about fundingThe author would like to acknowledge the Magnus Ehrnrooth Foundation and the University of Jyväskylä for funding this research.
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