The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6
Ward, J. S. (2022). The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6. CrystEngComm, 24(40), 7029-7033. https://doi.org/10.1039/d2ce01225a
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CrystEngCommDate
2022Copyright
© The Royal Society of Chemistry 2022
The first iodine(I) complex bearing hydrogen-bond donor and acceptor groups, [bis(3-acetaminopyridine)iodine(I)]PF6 (3), was synthesised, which exhibited two temperature-dependent solid-state connectivities of the hydrogen bonding. Upon reaction of 3 with tBuOMe, unprecedented iodination of a tBu methyl group proceeded under exceptionally mild conditions in good yield.
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Royal Society of Chemistry (RSC)ISSN Search the Publication Forum
1466-8033Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/156987273
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Academy Research Fellow, AoFAdditional information about funding
The author would like to acknowledge the Magnus Ehrnrooth Foundation and the University of Jyväskylä for funding this research.License
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