Nucleophilic Iodonium Interactions (NIIs) in 2-coordinate Iodine(I) and Silver(I) Complexes
Ward, J. S., Frontera, A., & Rissanen, K. (2021). Nucleophilic Iodonium Interactions (NIIs) in 2-coordinate Iodine(I) and Silver(I) Complexes. Chemical Communications, 57(41), 5094-5097. https://doi.org/10.1039/d1cc01505b
Julkaistu sarjassa
Chemical CommunicationsPäivämäärä
2021Tekijänoikeudet
© 2021 Royal Society of Chemistry
The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(I) and iodonium (I+) complexes and studying their 15N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(I) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.
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Royal Society of Chemistry (RSC)ISSN Hae Julkaisufoorumista
1359-7345Asiasanat
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https://converis.jyu.fi/converis/portal/detail/Publication/68034436
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We gratefully acknowledge the Finnish Cultural Foundation Central Fund (J. S. W. grant number 00201148), the Magnus Ehrnrooth Foundation (J. S. W.), the MICIU/AEI of Spain (A. F. project CTQ2017-85821-R FEDER), the Academy of Finland (K. R. grant no. 317259), and the University of Jyvaskyla, Finland for financial support.Lisenssi
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Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?
Wilcox, Scott; Sethio, Daniel; Ward, Jas S; Frontera, Antonio; Lindh, Roland; Rissanen, Kari; Erdelyi, Mate (Royal Society of Chemistry (RSC), 2022)The interaction of a [bis(pyridine)iodine(I)]+ cation with a [bis(pyridine)silver(I)]+ cation, in which an iodonium ion acts as nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. ... -
Linear bis‐Coordinate Silver(I) and Iodine(I) Complexes with R3R2R1N Tertiary Amines
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Iodine(I) and Silver(I) Complexes of Benzoimidazole and Pyridylcarbazole Derivatives
Rissanen, Kari; Taipale, Essi; Truong, Khai-Nghi; Siepmann, Marcel (Wiley, 2021)The synthesis of iodine(I) complexes with either benzoimidazole or carbazole-derived sp 2 N -containing Lewis bases is described, as well as their corresponding silver(I) complexes. The addition of elemental iodine to the ... -
Dimeric iodine(i) and silver(i) cages from tripodal N-donor ligands <i>via</i> the [N–Ag–N]+ to [N–I–N]+ cation exchange reaction
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