Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?
Wilcox, S., Sethio, D., Ward, J. S., Frontera, A., Lindh, R., Rissanen, K., & Erdelyi, M. (2022). Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?. Chemical Communications, 58(32), 4977-4980. https://doi.org/10.1039/D2CC00994C
Published inChemical Communications
DisciplineOrgaaninen kemiaOrganic Chemistry
© 2022 The Royal Society of Chemistry
The interaction of a [bis(pyridine)iodine(I)]+ cation with a [bis(pyridine)silver(I)]+ cation, in which an iodonium ion acts as nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. No measurable interaction is observed between the cationic species in solution by NMR; DFT reveals that if there is an attractive interaction between this complexes in solution, it is dominantly the π-π interaction of pyridines
PublisherRoyal Society of Chemistry (RSC)
ISSN Search the Publication Forum1359-7345
Publication in research information system
MetadataShow full item record
Additional information about fundingThis work was supported by Vetenskapsrådet [2020-03431; 2020-03182] and made use of the NMR Uppsala infrastructure, which is funded by the Department of Chemistry – BMC and the Disciplinary Domain of Medicine and Pharmacy. The computations were enabled by resources provided by the Swedish National Infrastructure for Computing (SNIC) through project SNIC 2021-5-359.
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