Nucleophilic Iodonium Interactions (NIIs) in 2-coordinate Iodine(I) and Silver(I) Complexes
Ward, J. S., Frontera, A., & Rissanen, K. (2021). Nucleophilic Iodonium Interactions (NIIs) in 2-coordinate Iodine(I) and Silver(I) Complexes. Chemical Communications, 57(41), 5094-5097. https://doi.org/10.1039/d1cc01505b
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Chemical CommunicationsDate
2021Copyright
© 2021 Royal Society of Chemistry
The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(I) and iodonium (I+) complexes and studying their 15N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(I) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.
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Royal Society of Chemistry (RSC)ISSN Search the Publication Forum
1359-7345Keywords
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https://converis.jyu.fi/converis/portal/detail/Publication/68034436
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Academy of FinlandFunding program(s)
Academy Project, AoF![](/themes/JYX2/images/funders/sa_logo_thumb.jpg)
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We gratefully acknowledge the Finnish Cultural Foundation Central Fund (J. S. W. grant number 00201148), the Magnus Ehrnrooth Foundation (J. S. W.), the MICIU/AEI of Spain (A. F. project CTQ2017-85821-R FEDER), the Academy of Finland (K. R. grant no. 317259), and the University of Jyvaskyla, Finland for financial support.License
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