Nucleophilic Iodonium Interactions (NIIs) in 2-coordinate Iodine(I) and Silver(I) Complexes
Ward, J. S., Frontera, A., & Rissanen, K. (2021). Nucleophilic Iodonium Interactions (NIIs) in 2-coordinate Iodine(I) and Silver(I) Complexes. Chemical Communications, 57(41), 5094-5097. https://doi.org/10.1039/d1cc01505b
Published inChemical Communications
© 2021 Royal Society of Chemistry
The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(I) and iodonium (I+) complexes and studying their 15N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(I) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.
PublisherRoyal Society of Chemistry (RSC)
Publication in research information system
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Related funder(s)Academy of Finland
Funding program(s)Academy Project, AoF
Additional information about fundingWe gratefully acknowledge the Finnish Cultural Foundation Central Fund (J. S. W. grant number 00201148), the Magnus Ehrnrooth Foundation (J. S. W.), the MICIU/AEI of Spain (A. F. project CTQ2017-85821-R FEDER), the Academy of Finland (K. R. grant no. 317259), and the University of Jyvaskyla, Finland for financial support.
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