Nucleophilic Iodonium Interactions (NIIs) in 2-coordinate Iodine(I) and Silver(I) Complexes
Ward, J. S., Frontera, A., & Rissanen, K. (2021). Nucleophilic Iodonium Interactions (NIIs) in 2-coordinate Iodine(I) and Silver(I) Complexes. Chemical Communications, 57(41), 5094-5097. https://doi.org/10.1039/d1cc01505b
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Chemical CommunicationsDate
2021Copyright
© 2021 Royal Society of Chemistry
The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(I) and iodonium (I+) complexes and studying their 15N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(I) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.
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Royal Society of Chemistry (RSC)ISSN Search the Publication Forum
1359-7345Keywords
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https://converis.jyu.fi/converis/portal/detail/Publication/68034436
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Academy of FinlandFunding program(s)
Academy Project, AoF
Additional information about funding
We gratefully acknowledge the Finnish Cultural Foundation Central Fund (J. S. W. grant number 00201148), the Magnus Ehrnrooth Foundation (J. S. W.), the MICIU/AEI of Spain (A. F. project CTQ2017-85821-R FEDER), the Academy of Finland (K. R. grant no. 317259), and the University of Jyvaskyla, Finland for financial support.License
Except where otherwise noted, this item's license is described as CC BY-NC 4.0