dc.contributor.author | Zhu, Qihao | |
dc.contributor.author | Fettinger, James C. | |
dc.contributor.author | Vasko, Petra | |
dc.contributor.author | Power, Philip P. | |
dc.date.accessioned | 2020-12-15T09:21:34Z | |
dc.date.available | 2020-12-15T09:21:34Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Zhu, Q., Fettinger, J. C., Vasko, P., & Power, P. P. (2020). Interactions of a Diplumbyne with Dinuclear Transition Metal Carbonyls to Afford Metalloplumbylenes. <i>Organometallics</i>, <i>39</i>(24), 4629-4636. <a href="https://doi.org/10.1021/acs.organomet.0c00659" target="_blank">https://doi.org/10.1021/acs.organomet.0c00659</a> | |
dc.identifier.other | CONVID_47317091 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/73199 | |
dc.description.abstract | The metathesis reactions of the diplumbyne AriPr6PbPbAriPr6 (AriPr6 = −C6H3–2,6-(C6H2–2,4,6-iPr3)2) with the dinuclear metal carbonyls Mn2(CO)10, Fe2(CO)9, and Co2(CO)8 under mild conditions afforded the complexes Mn(CO)5(PbAriPr6) (1), Fe(CO)4(PbAriPr6)2 (2), and Co4(CO)9(PbAriPr6)2 (3), respectively. Complexes 1–3 were structurally characterized by single-crystal X-ray diffraction and spectroscopically characterized by 1H, 13C{1H}, 59Co{1H}, and 207Pb{1H} NMR; UV–vis; and IR methods. They are rare examples of species formed by the direct reaction of a group 14 dimetallyne with transition metal carbonyls. Complexes 1 and 2 feature Mn–Pb or Fe–Pb single bonds, whereas in 3 a Co–Pb cluster is formed in which the plumbylidyne moiety bridges either an edge or a face of a Co4 carbonyl cluster. | en |
dc.format.mimetype | application/pdf | |
dc.language | eng | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society (ACS) | |
dc.relation.ispartofseries | Organometallics | |
dc.rights | In Copyright | |
dc.subject.other | metals | |
dc.subject.other | carbonyls | |
dc.subject.other | transition metals | |
dc.subject.other | cobalt | |
dc.subject.other | nuclear magnetic resonance spectroscopy | |
dc.title | Interactions of a Diplumbyne with Dinuclear Transition Metal Carbonyls to Afford Metalloplumbylenes | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202012157146 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 4629-4636 | |
dc.relation.issn | 0276-7333 | |
dc.relation.numberinseries | 24 | |
dc.relation.volume | 39 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2020 American Chemical Society | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 314794 | |
dc.subject.yso | karbonyylit | |
dc.subject.yso | organometalliyhdisteet | |
dc.subject.yso | kompleksiyhdisteet | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p14898 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p28123 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
dc.relation.doi | 10.1021/acs.organomet.0c00659 | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Suomen Akatemia | fi |
jyx.fundingprogram | Postdoctoral Researcher, AoF | en |
jyx.fundingprogram | Tutkijatohtori, SA | fi |
jyx.fundinginformation | We are grateful to the National Science Foundation (NSF) for financial support (Grant CHE-1565501) and the dual-source X-ray diffractometer (Grant 0840444). P.V. would like to thank the Academy of Finland (project number 314794) and Prof. Heikki M. Tuononen for providing computational resources. | |
dc.type.okm | A1 | |