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dc.contributor.authorSiitonen, Juha
dc.contributor.authorYu, Lu
dc.contributor.authorDanielsson, Jakob
dc.contributor.authorGregorio, Giovanni Di
dc.contributor.authorSomfai, Peter
dc.date.accessioned2018-09-26T09:40:07Z
dc.date.available2019-07-18T21:35:22Z
dc.date.issued2018
dc.identifier.citationSiitonen, J., Yu, L., Danielsson, J., Gregorio, G. D., & Somfai, P. (2018). Formal synthesis of ent-Cephalotaxine using a one-pot Parham-aldol sequence. <i>Journal of Organic Chemistry</i>, <i>83</i>(18), 11318-11322. <a href="https://doi.org/10.1021/acs.joc.8b01540" target="_blank">https://doi.org/10.1021/acs.joc.8b01540</a>
dc.identifier.otherCONVID_28184757
dc.identifier.otherTUTKAID_78385
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/59681
dc.description.abstractA short formal synthesis of ent-Cephalotaxine is achieved. The approach features a new Lewis acid mediated [2,3]-Stevens rearrangement of N-allylated prolineamide to generate a key quaternary stereogenic center. Additionally, a one-pot Parham–aldol sequence was developed to rapidly assembly two of the four rings in the cephalotaxine core.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesJournal of Organic Chemistry
dc.rightsIn Copyright
dc.subject.otherformal synthesis
dc.titleFormal synthesis of ent-Cephalotaxine using a one-pot Parham-aldol sequence
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201809214206
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-09-21T09:15:11Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange11318-11322
dc.relation.issn0022-3263
dc.relation.numberinseries18
dc.relation.volume83
dc.type.versionacceptedVersion
dc.rights.copyright© American Chemical Society, 2018
dc.rights.accesslevelopenAccessfi
dc.subject.ysoluonnonaineet
dc.subject.ysoalkaloidit
dc.subject.ysokemiallinen synteesi
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p6956
jyx.subject.urihttp://www.yso.fi/onto/yso/p11306
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1021/acs.joc.8b01540
dc.type.okmA1


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