dc.contributor.author | Vasko, Petra | |
dc.contributor.author | Hurmalainen, Juha | |
dc.contributor.author | Mansikkamäki, Akseli | |
dc.contributor.author | Peuronen, Anssi | |
dc.contributor.author | Mailman, Aaron | |
dc.contributor.author | Tuononen, Heikki | |
dc.date.accessioned | 2017-12-01T10:06:03Z | |
dc.date.available | 2017-12-01T10:06:03Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Vasko, P., Hurmalainen, J., Mansikkamäki, A., Peuronen, A., Mailman, A., & Tuononen, H. (2017). Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement. <i>Dalton Transactions</i>, <i>46</i>(46), 16004-16008. <a href="https://doi.org/10.1039/c7dt03243a" target="_blank">https://doi.org/10.1039/c7dt03243a</a> | |
dc.identifier.other | CONVID_27333692 | |
dc.identifier.other | TUTKAID_75596 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/56080 | |
dc.description.abstract | The condensation reaction of 2-aminobenzenethiols and 3-aminopyrazinethiols
with 2-amino-6-fluoro-N-methylpyridinium triflate
afforded thioether derivatives that were found to undergo Smiles
rearrangement and cyclocondensation with sulphur monochloride
to yield new hybrid 1,4-thiazine-1,2,3-dithiazolylium cations. The
synthesized cations were readily reduced to the corresponding
stable neutral radicals with spin densities delocalized over both
1,4-thiazinyl and 1,2,3-dithiazolyl moieties. | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.relation.ispartofseries | Dalton Transactions | |
dc.subject.other | 1,4-thiazinyl-1,2,3-dithiazolyl radicals | |
dc.subject.other | Smiles rearrangement | |
dc.title | Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201711294424 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2017-11-29T13:15:15Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 16004-16008 | |
dc.relation.issn | 1477-9226 | |
dc.relation.numberinseries | 46 | |
dc.relation.volume | 46 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © The Royal Society of Chemistry 2017. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 289172 | |
dc.relation.grantnumber | 659123 | |
dc.relation.grantnumber | 659123 | |
dc.relation.projectid | info:eu-repo/grantAgreement/EC/H2020/659123/EU// | |
dc.subject.yso | synteesi | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p8467 | |
dc.rights.url | https://creativecommons.org/licenses/by-nc/3.0/ | |
dc.relation.doi | 10.1039/c7dt03243a | |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Euroopan komissio | fi |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | European Commission | en |
jyx.fundingprogram | Akatemiahanke, SA | fi |
jyx.fundingprogram | MSCA Marie Skłodowska-Curie Actions, H2020 | fi |
jyx.fundingprogram | Academy Project, AoF | en |
jyx.fundingprogram | MSCA Marie Skłodowska-Curie Actions, H2020 | en |
jyx.fundinginformation | This work was financially supported by the University of Jyväskylä, the Academy of Finland (projects 253907 and
289172) and the European Union’s H2020 programme (under the Marie Skłodowska-Curie grant agreement 659123). We thank Laboratory Technicians Johanna Lind and Elina Hautakangas for running the +ESI-MS and EA measurements,
respectively. | |
dc.type.okm | A1 | |