Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct
Abstract
The solid and solution state structure of the vanadium(II) N‐
heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported
(
SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐
en‐2‐ylidene). The electronic structure of 1 is probed using
combination of magnetic measurements, EPR spectroscopy and
computational studies. The V–Si bond strength and complex
forming mechanism between vanadocene and NHSi ligand is
elucidated using computational methods.
Main Authors
Format
Articles
Research article
Published
2017
Series
Subjects
Publication in research information system
Publisher
Royal Society of Chemistry
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201708073424Use this for linking
Review status
Peer reviewed
ISSN
1477-9226
DOI
https://doi.org/10.1039/C7DT01226H
Language
English
Published in
Dalton Transactions
Citation
- Hänninen, M. M., Baldansuren, A., & Pugh, T. (2017). Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct. Dalton Transactions, 46(30), 9740-9744. https://doi.org/10.1039/C7DT01226H
License
Copyright© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.