Review: monoclinic zirconia, its surface sites and their interaction with carbon monoxide
Kouva, S., Honkala, K., Lefferts, L., & Kanervo, J. (2015). Review: monoclinic zirconia, its surface sites and their interaction with carbon monoxide. Catalysis Science & Technology, 5(7), 3473-3490. https://doi.org/10.1039/C5CY00330J
Julkaistu sarjassa
Catalysis Science & TechnologyPäivämäärä
2015Tekijänoikeudet
© Royal Society of Chemistry, 2015. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
This review concerns monoclinic zirconia, its surface sites and their probing with carbon monoxide. The surface sites and their
modifications using thermal treatments with vacuum or reactive gases are also included. In this work, we present information
on the nature and manipulation of hydroxyl species and their quantities on the surface, the different types of cationic sites where
CO is adsorbed linearly and their energetics, as well as the surface sites and dynamics of formate formation. We also compare
the surface concentrations of the different surface species to better understand the extent and nature of the interactions. Finally,
we discuss some of the remaining open questions and how to approach them.
Julkaisija
RSC PublicationsISSN Hae Julkaisufoorumista
2044-4753Asiasanat
Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/24787959
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