Review: monoclinic zirconia, its surface sites and their interaction with carbon monoxide
Abstract
This review concerns monoclinic zirconia, its surface sites and their probing with carbon monoxide. The surface sites and their
modifications using thermal treatments with vacuum or reactive gases are also included. In this work, we present information
on the nature and manipulation of hydroxyl species and their quantities on the surface, the different types of cationic sites where
CO is adsorbed linearly and their energetics, as well as the surface sites and dynamics of formate formation. We also compare
the surface concentrations of the different surface species to better understand the extent and nature of the interactions. Finally,
we discuss some of the remaining open questions and how to approach them.
Main Authors
Format
Articles
Review article
Published
2015
Series
Subjects
Publication in research information system
Publisher
RSC Publications
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201707063255Use this for linking
Review status
Peer reviewed
ISSN
2044-4753
DOI
https://doi.org/10.1039/C5CY00330J
Language
English
Published in
Catalysis Science & Technology
Citation
- Kouva, S., Honkala, K., Lefferts, L., & Kanervo, J. (2015). Review: monoclinic zirconia, its surface sites and their interaction with carbon monoxide. Catalysis Science & Technology, 5(7), 3473-3490. https://doi.org/10.1039/C5CY00330J
License
Copyright© Royal Society of Chemistry, 2015. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.