Crystal structure of the borabenzene-2,6-lutidine adduct
Kivijärvi, L., & Haukka, M. (2015). Crystal structure of the borabenzene-2,6-lutidine adduct. Acta Crystallographica Section E : Crystallographic Communications, 71(12), Article o944. https://doi.org/10.1107/S2056989015020599
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Acta Crystallographica Section E : Crystallographic CommunicationsPäivämäärä
2015Tekijänoikeudet
© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
In the title compound, C12H14BN, the complete molecule is
generated by a crystallographic twofold axis, with two C
atoms, the B atom and the N atom lying on the rotation axis.
The dihedral angle between the borabenzene and pyridine
rings is 81.20 (6). As well as dative electron donation from the
N atom to the B atom [B—N = 1.5659 (18) A˚ ], the methyl
substituents on the lutidine ring shield the B atom, which
further stabilizes the molecule. In the crystal, weak aromatic
– stacking between the pyridine rings [centroid–centroid
separation = 3.6268 (9) A˚ ] is observed, which generates [001]
columns of molecules.
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International Union of CrystallographyISSN Hae Julkaisufoorumista
2056-9890Asiasanat
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