Näytä suppeat kuvailutiedot

dc.contributor.authorKivijärvi, Lauri
dc.contributor.authorHaukka, Matti
dc.date.accessioned2016-04-05T09:54:01Z
dc.date.available2016-04-05T09:54:01Z
dc.date.issued2015
dc.identifier.citationKivijärvi, L., & Haukka, M. (2015). Crystal structure of the bora­benzene-2,6-lutidine adduct. <i>Acta Crystallographica Section E : Crystallographic Communications</i>, <i>71</i>(12), Article o944. <a href="https://doi.org/10.1107/S2056989015020599" target="_blank">https://doi.org/10.1107/S2056989015020599</a>
dc.identifier.otherCONVID_25533647
dc.identifier.otherTUTKAID_69102
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/49255
dc.description.abstractIn the title compound, C12H14BN, the complete molecule is generated by a crystallographic twofold axis, with two C atoms, the B atom and the N atom lying on the rotation axis. The dihedral angle between the borabenzene and pyridine rings is 81.20 (6). As well as dative electron donation from the N atom to the B atom [B—N = 1.5659 (18) A˚ ], the methyl substituents on the lutidine ring shield the B atom, which further stabilizes the molecule. In the crystal, weak aromatic – stacking between the pyridine rings [centroid–centroid separation = 3.6268 (9) A˚ ] is observed, which generates [001] columns of molecules.
dc.language.isoeng
dc.publisherInternational Union of Crystallography
dc.relation.ispartofseriesActa Crystallographica Section E : Crystallographic Communications
dc.subject.othercrystal structure
dc.subject.otherbora­benzene
dc.subject.other[pi]-[pi] stacking
dc.titleCrystal structure of the bora­benzene-2,6-lutidine adduct
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201604052003
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2016-04-05T09:15:05Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.relation.issn2056-9890
dc.relation.numberinseries12
dc.relation.volume71
dc.type.versionpublishedVersion
dc.rights.copyright© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
dc.rights.accesslevelopenAccessfi
dc.rights.urlhttp://creativecommons.org/licenses/by/2.0/uk/legalcode
dc.relation.doi10.1107/S2056989015020599
dc.type.okmA1


Aineistoon kuuluvat tiedostot

Thumbnail

Aineisto kuuluu seuraaviin kokoelmiin

Näytä suppeat kuvailutiedot

© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
Ellei muuten mainita, aineiston lisenssi on © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.