Crystal structure of the borabenzene-2,6-lutidine adduct
| dc.contributor.author | Kivijärvi, Lauri | |
| dc.contributor.author | Haukka, Matti | |
| dc.date.accessioned | 2016-04-05T09:54:01Z | |
| dc.date.available | 2016-04-05T09:54:01Z | |
| dc.date.issued | 2015 | |
| dc.identifier.citation | Kivijärvi, L., & Haukka, M. (2015). Crystal structure of the borabenzene-2,6-lutidine adduct. <i>Acta Crystallographica Section E : Crystallographic Communications</i>, <i>71</i>(12), Article o944. <a href="https://doi.org/10.1107/S2056989015020599" target="_blank">https://doi.org/10.1107/S2056989015020599</a> | |
| dc.identifier.other | CONVID_25533647 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/49255 | |
| dc.description.abstract | In the title compound, C12H14BN, the complete molecule is generated by a crystallographic twofold axis, with two C atoms, the B atom and the N atom lying on the rotation axis. The dihedral angle between the borabenzene and pyridine rings is 81.20 (6). As well as dative electron donation from the N atom to the B atom [B—N = 1.5659 (18) A˚ ], the methyl substituents on the lutidine ring shield the B atom, which further stabilizes the molecule. In the crystal, weak aromatic – stacking between the pyridine rings [centroid–centroid separation = 3.6268 (9) A˚ ] is observed, which generates [001] columns of molecules. | |
| dc.language.iso | eng | |
| dc.publisher | International Union of Crystallography | |
| dc.relation.ispartofseries | Acta Crystallographica Section E : Crystallographic Communications | |
| dc.subject.other | crystal structure | |
| dc.subject.other | borabenzene | |
| dc.subject.other | [pi]-[pi] stacking | |
| dc.title | Crystal structure of the borabenzene-2,6-lutidine adduct | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201604052003 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2016-04-05T09:15:05Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.relation.issn | 2056-9890 | |
| dc.relation.numberinseries | 12 | |
| dc.relation.volume | 71 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.rights.url | http://creativecommons.org/licenses/by/2.0/uk/legalcode | |
| dc.relation.doi | 10.1107/S2056989015020599 | |
| dc.type.okm | A1 |
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