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dc.contributor.authorShylin, Sergii I.
dc.contributor.authorGural skiy, Il ya A.
dc.contributor.authorHaukka, Matti
dc.contributor.authorGolenya, Irina A.
dc.date.accessioned2016-02-04T12:49:23Z
dc.date.available2016-02-04T12:49:23Z
dc.date.issued2013
dc.identifier.citationShylin, S. I., Gural’skiy, I. A., Haukka, M., & Golenya, I. A. (2013). Pyridinium bis(pyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) -pyrazine-2-carbonitrile-pyridine (1/4/1). <em>Acta Crystallographica Section E : Structure Reports Online</em>, 69 (5), m280. <a href="http://dx.doi.org/10.1107/S1600536813010362">doi:10.1107/S1600536813010362</a>
dc.identifier.otherTUTKAID_63068
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/48629
dc.description.abstractIn the title compound, (C5H6N)[Fe(NCS)4(C5H5N)2]- 4C5H3N3C5H5N, the FeIII ion is located on an inversion centre and is six-coordinated by four N atoms of the thiocyanate ligands and two pyridine N atoms in a trans arrangement, forming a slightly distorted octahedral geometry. A half-occupied H atom attached to a pyridinium cation forms an N—HN hydrogen bond with a centrosymmetrically-related pyridine unit. Four pyrazine-2-carbonitrile molecules crystallize per complex anion. In the crystal, – stacking interactions are present [centroid–centroid distances = 3.6220 (9), 3.6930 (9), 3.5532 (9), 3.5803 (9) and 3.5458 (8) A˚ ].
dc.language.isoeng
dc.publisherWiley-Blackwell Publishing, Inc.
dc.relation.ispartofseriesActa Crystallographica Section E : Structure Reports Online
dc.subject.otherPyridinium
dc.titlePyridinium bis(pyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) -pyrazine-2-carbonitrile-pyridine (1/4/1)
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201602041436
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2016-02-04T10:15:02Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerangem280
dc.relation.issn1600-5368
dc.relation.volume69
dc.type.versionpublishedVersion
dc.rights.copyright© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
dc.rights.accesslevelopenAccessfi
dc.rights.urlhttp://creativecommons.org/licenses/by/2.0/uk/legalcode
dc.relation.doi10.1107/S1600536813010362


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© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
Except where otherwise noted, this item's license is described as © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.