Pyridinium bis(pyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) -pyrazine-2-carbonitrile-pyridine (1/4/1)
Shylin, S. I., Gural’skiy, I. A., Haukka, M., & Golenya, I. A. (2013). Pyridinium bis(pyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) -pyrazine-2-carbonitrile-pyridine (1/4/1). Acta Crystallographica Section E : Structure Reports Online, 69(5), m280. https://doi.org/10.1107/S1600536813010362
Date
2013Copyright
© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
In the title compound, (C5H6N)[Fe(NCS)4(C5H5N)2]-
4C5H3N3C5H5N, the FeIII ion is located on an inversion
centre and is six-coordinated by four N atoms of the
thiocyanate ligands and two pyridine N atoms in a trans
arrangement, forming a slightly distorted octahedral
geometry. A half-occupied H atom attached to a pyridinium
cation forms an N—HN hydrogen bond with a centrosymmetrically-related
pyridine unit. Four pyrazine-2-carbonitrile
molecules crystallize per complex anion. In the crystal, –
stacking interactions are present [centroid–centroid distances
= 3.6220 (9), 3.6930 (9), 3.5532 (9), 3.5803 (9) and
3.5458 (8) A˚ ].
Publisher
Wiley-Blackwell Publishing, Inc.ISSN Search the Publication Forum
1600-5368Keywords
Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/23884802
Metadata
Show full item recordCollections
License
Except where otherwise noted, this item's license is described as © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
Related items
Showing items with similar title or keywords.
-
Pyridinium bis(pyridine-jN)tetrakis(thiocyanato-cyanato-jN)ferrate(III)
Shylin, S. I.; Gural'skiy, I. A.; Haukka, Matti; Kapshuk, A. A.; Prisyazhnaya, E. V. (Wiley-Blackwell Publishing, Inc., 2013)In the title compound, (C5H6N)[Fe(NCS)4(C5H5N)2], the FeIII ion is coordinated by four thiocyanate N atoms and two pyridine N atoms in a trans arrangement, forming an FeN6 polyhedron with a slightly distorted octahedral ... -
Second order nonlinear optical activity of amino acids, guanidines and pyridinium salts of inorganic anions
Ayeah, Vera (2019)The present work is committed to organic nonlinear optical materials (NLO materials) and their prospective applications. The literary part consists of the theoretical background of organic NLO materials. Properties of ... -
6-Amino-2-(pivaloylamino)pyridinium benzoate
Checinska, Lilianna; Osmialowski, Borys; Valkonen, Arto (International Union of Crystallography, 2013)In the crystal structure of the title salt, C₁₀H₁₆N₃O⁺·C₇H₅O₂ˉ, the cations and anions are linked to each other via N-H...O hydrogen bonds, forming infinite chains running along [010]. The crystal structure also features ... -
Anthracene Fluorescence Quenching by a Tetrakis (Ketocarboxamide) Cavitand
Janosi, Tibor Zoltan; Korppi-Tommola, Jouko; Csok, Zsolt; Kollar, Laszlo; Myllyperkiö, Pasi; Erostyak, Janos (Hindawi Publishing Corporation, 2014)Quenching of both fluorescence lifetime and fluorescence intensity of anthracene was investigated in the presence of a newly derived tetrakis (ketocarboxamide) cavitand at various concentrations. Time-correlated single ... -
N2,N2.N6,N6-Tetrakis(perfluorobenzoyl)-2,6-diaminopyridine
Valkonen, Arto; Kolehmainen, Erkki; Osmialowski, Borys (IuCr, 2011)The title compound, C³³H³F²⁰N³O⁴, is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diaminopyridine with 2,3,4,5,6-pentafluorobenzoyl chloride in a 1:2 molar ratio. ...