Pyridinium bis(pyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) -pyrazine-2-carbonitrile-pyridine (1/4/1)
Shylin, S. I., Gural’skiy, I. A., Haukka, M., & Golenya, I. A. (2013). Pyridinium bis(pyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) -pyrazine-2-carbonitrile-pyridine (1/4/1). Acta Crystallographica Section E : Structure Reports Online, 69(5), m280. https://doi.org/10.1107/S1600536813010362
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In the title compound, (C5H6N)[Fe(NCS)4(C5H5N)2]- 4C5H3N3C5H5N, the FeIII ion is located on an inversion centre and is six-coordinated by four N atoms of the thiocyanate ligands and two pyridine N atoms in a trans arrangement, forming a slightly distorted octahedral geometry. A half-occupied H atom attached to a pyridinium cation forms an N—HN hydrogen bond with a centrosymmetrically-related pyridine unit. Four pyrazine-2-carbonitrile molecules crystallize per complex anion. In the crystal, – stacking interactions are present [centroid–centroid distances = 3.6220 (9), 3.6930 (9), 3.5532 (9), 3.5803 (9) and 3.5458 (8) A˚ ].
PublisherWiley-Blackwell Publishing, Inc.
ISSN Search the Publication Forum1600-5368
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