Pyridinium bis(pyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) -pyrazine-2-carbonitrile-pyridine (1/4/1)
Shylin, S. I., Gural’skiy, I. A., Haukka, M., & Golenya, I. A. (2013). Pyridinium bis(pyridine-κN)tetrakis(thiocyanato-κN)ferrate(III) -pyrazine-2-carbonitrile-pyridine (1/4/1). Acta Crystallographica Section E : Structure Reports Online, 69(5), m280. https://doi.org/10.1107/S1600536813010362
Date
2013Copyright
© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
In the title compound, (C5H6N)[Fe(NCS)4(C5H5N)2]-
4C5H3N3C5H5N, the FeIII ion is located on an inversion
centre and is six-coordinated by four N atoms of the
thiocyanate ligands and two pyridine N atoms in a trans
arrangement, forming a slightly distorted octahedral
geometry. A half-occupied H atom attached to a pyridinium
cation forms an N—HN hydrogen bond with a centrosymmetrically-related
pyridine unit. Four pyrazine-2-carbonitrile
molecules crystallize per complex anion. In the crystal, –
stacking interactions are present [centroid–centroid distances
= 3.6220 (9), 3.6930 (9), 3.5532 (9), 3.5803 (9) and
3.5458 (8) A˚ ].
Publisher
Wiley-Blackwell Publishing, Inc.ISSN Search the Publication Forum
1600-5368Keywords
Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/23884802
Metadata
Show full item recordCollections
License
Except where otherwise noted, this item's license is described as © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
Related items
Showing items with similar title or keywords.
-
How to fight multiple enemies : target-specific chemical defences in an aposematic moth
Rojas Zuluaga, Bibiana; Burdfield-Steel, Emily; Pakkanen, Hannu; Suisto, Kaisa; Maczka, Michael; Schulz, Stefan; Mappes, Johanna (The Royal Society Publishing, 2017)Animals have evolved different defensive strategies to survive predation, among which chemical defences are particularly widespread and diverse. Here we investigate the function of chemical defence diversity, hypothesizing ... -
De novo Synthesis of Chemical Defenses in an Aposematic Moth
Burdfield-Steel, Emily; Pakkanen, Hannu; Rojas Zuluaga, Bibiana; Galarza, Juan; Mappes, Johanna (Oxford University Press, 2018)Many animals protect themselves from predation with chemicals, both self-made or sequestered from their diet. The potential drivers of the diversity of these chemicals have been long studied, but our knowledge of these ... -
Testing the effectiveness of pyrazine defences against spiders
Burdfield-Steel, Emily R.; Schneider, Jutta M.; Mappes, Johanna; Dobler, Susanne (Springer, 2020)Insects live in a dangerous world and may fall prey to a wide variety of predators, encompassing multiple taxa. As a result, selection may favour defences that are effective against multiple predator types, or target-specific ... -
Hydrogen and Halogen Bond Mediated Coordination Polymers of Chloro-Substituted Pyrazin-2-Amine Copper(I) Bromide Complexes
Mailman, Aaron; Puttreddy, Rakesh; Lahtinen, Manu; Svahn, Noora; Rissanen, Kari (MDPI AG, 2020)A new class of six mono- (1; 3-Cl-, 2; 5-Cl-, 3; 6-Cl-) and di-(4; 3,6-Cl, 5; 5,6-Cl-, 6; 3,5-Cl-) chloro-substituted pyrazin-2-amine ligands (1–6) form complexes with copper (I) bromide, to give 1D and 2D coordination ... -
Simultaneous Endo- and Exo-Complex Formation of Pyridine[4]arene Dimer with Neutral and Anionic Guests
Kiesilä, Anniina; Kivijärvi, Lauri; Beyeh, Ngong Kodiah; Moilanen, Jani; Groessl, Michael; Rothe, Tatiana; Götz, Sven; Topic, Filip; Rissanen, Kari; Lützen, Arne; Kalenius, Elina (Wiley-VCH, 2017)The formation of complexes between hexafluorophosphate (PF6−) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI‐QTOF‐MS, IM‐MS, DFT calculations), in the solid state (X‐ray ...