Pyridinium bis(pyridine-jN)tetrakis(thiocyanato-cyanato-jN)ferrate(III)
Shylin, S. I., Gural'skiy, I. A., Haukka, M., Kapshuk, A.A., & Prisyazhnaya, E. V. (2013). Pyridinium bis(pyridine-jN)tetrakis(thiocyanato-cyanato-jN)ferrate(III). Acta Crystallographica Section E : Structure Reports Online, 69(6), m298-m299. https://doi.org/10.1107/S1600536813011628
Date
2013Copyright
© International Union of Crystallography. Published in this repository with the kind permission of the publisher.
In the title compound, (C5H6N)[Fe(NCS)4(C5H5N)2], the FeIII
ion is coordinated by four thiocyanate N atoms and two
pyridine N atoms in a trans arrangement, forming an FeN6
polyhedron with a slightly distorted octahedral geometry.
Charge balance is achieved by one pyridinium cation bound to
the complex anion via N—HS hydrogen bonding. The
asymmetric unit consists of one FeIII cation, four thiocyanate
anions, two coordinated pyridine molecules and one pyridinium
cation. The structure exhibits – interactions between
pyridine rings [centroid–centroid distances = 3.7267 (2),
3.7811 (2) and 3.8924 (2) A˚ ]. The N atom and a neighboring
C atom of the pyridinium cation are statistically disordered
with an occupancy ratio of 0.58 (2):0.42 (2).
Publisher
Wiley-Blackwell Publishing, Inc.ISSN Search the Publication Forum
1600-5368Keywords
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https://converis.jyu.fi/converis/portal/detail/Publication/23876224
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