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Pyridinium bis(pyridine-jN)tetrakis(thiocyanato-cyanato-jN)ferrate(III)

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Shylin, S. I., Gural'skiy, I. A., Haukka, M., Kapshuk, A.A., & Prisyazhnaya, E. V. (2013). Pyridinium bis(pyridine-jN)tetrakis(thiocyanato-cyanato-jN)ferrate(III). Acta Crystallographica Section E : Structure Reports Online, 69(6), m298-m299. https://doi.org/10.1107/S1600536813011628
Published in
Acta Crystallographica Section E : Structure Reports Online
Authors
Shylin, S. I. |
Gural'skiy, I. A. |
Haukka, Matti |
Kapshuk, A. A. |
Prisyazhnaya, E. V.
Date
2013
Discipline
Epäorgaaninen ja analyyttinen kemiaInorganic and Analytical Chemistry
Copyright
© International Union of Crystallography. Published in this repository with the kind permission of the publisher.

 
In the title compound, (C5H6N)[Fe(NCS)4(C5H5N)2], the FeIII ion is coordinated by four thiocyanate N atoms and two pyridine N atoms in a trans arrangement, forming an FeN6 polyhedron with a slightly distorted octahedral geometry. Charge balance is achieved by one pyridinium cation bound to the complex anion via N—HS hydrogen bonding. The asymmetric unit consists of one FeIII cation, four thiocyanate anions, two coordinated pyridine molecules and one pyridinium cation. The structure exhibits – interactions between pyridine rings [centroid–centroid distances = 3.7267 (2), 3.7811 (2) and 3.8924 (2) A˚ ]. The N atom and a neighboring C atom of the pyridinium cation are statistically disordered with an occupancy ratio of 0.58 (2):0.42 (2).
Publisher
Wiley-Blackwell Publishing, Inc.
ISSN Search the Publication Forum
1600-5368
Keywords
Pyridinium
DOI
https://doi.org/10.1107/S1600536813011628
URI

http://urn.fi/URN:NBN:fi:jyu-201602041439

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/23876224

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