Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis

Abdel-Magied, Ahmed F.; Singh, Amrendra K.; Haukka, Matti; Richmond, Michael G.; Nordlander, Ebbe

doi:10.1039/c4cc02319f

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Abdel-Magied, A. F., Singh, A. K., Haukka, M., Richmond, M. G., & Nordlander, E. (2014). Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis. Chemical Communications, 50(57), 7705-7708. https://doi.org/10.1039/c4cc02319f

Julkaistu sarjassa

Chemical Communications

Tekijät

Abdel-Magied, Ahmed F. |

Singh, Amrendra K. |

Haukka, Matti |

Richmond, Michael G. |

Nordlander, Ebbe

Päivämäärä

2014

Oppiaine

Epäorgaaninen ja analyyttinen kemia Inorganic and Analytical Chemistry

Tekijänoikeudet

© The Royal Society of Chemistry 2014. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.

Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P–P*)] (P–P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.

Julkaisija

R S C Publications

ISSN Hae Julkaisufoorumista

1359-7345

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