Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis
Abstract
Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P–P*)] (P–P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.
Main Authors
Format
Articles
Research article
Published
2014
Series
Subjects
Publication in research information system
Publisher
R S C Publications
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201602041437Use this for linking
Review status
Peer reviewed
ISSN
1359-7345
DOI
https://doi.org/10.1039/c4cc02319f
Language
English
Published in
Chemical Communications
Citation
- Abdel-Magied, A. F., Singh, A. K., Haukka, M., Richmond, M. G., & Nordlander, E. (2014). Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis. Chemical Communications, 50(57), 7705-7708. https://doi.org/10.1039/c4cc02319f
License
Copyright© The Royal Society of Chemistry 2014. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.