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Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis

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Abdel-Magied, A. F., Singh, A. K., Haukka, M., Richmond, M. G., & Nordlander, E. (2014). Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis. Chemical Communications, 50(57), 7705-7708. https://doi.org/10.1039/c4cc02319f
Published in
Chemical Communications
Authors
Abdel-Magied, Ahmed F. |
Singh, Amrendra K. |
Haukka, Matti |
Richmond, Michael G. |
Nordlander, Ebbe
Date
2014
Discipline
Epäorgaaninen ja analyyttinen kemiaInorganic and Analytical Chemistry
Copyright
© The Royal Society of Chemistry 2014. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.

 
Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P–P*)] (P–P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.
Publisher
R S C Publications
ISSN Search the Publication Forum
1359-7345
Keywords
hydrogenation catalysis triruthenium clusters intact
DOI
https://doi.org/10.1039/c4cc02319f
URI

http://urn.fi/URN:NBN:fi:jyu-201602041437

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/23758306

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