N-[2-(2,2-Dimethylpropanamido)- pyrimidin-4-yl]-2,2-dimethyl- propanamide n-hexane 0.25-solvate hemihydrate
Osmialowski, B., Valkonen, A., & Checinska, L. (2013). N-[2-(2,2-Dimethylpropanamido)- pyrimidin-4-yl]-2,2-dimethyl- propanamide n-hexane 0.25-solvate hemihydrate. Acta Crystallographica Section E : Structure Reports Online, 69(11), o1617-o1618. https://doi.org/10.1107/S160053681302713X
Julkaistu sarjassa
Acta Crystallographica Section E : Structure Reports OnlinePäivämäärä
2013Tekijänoikeudet
© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
The asymmetric unit of the title compound, C₁₄H₂₂N₄O₂·0.25C₆H₁₄·0.5H₂O, contains two independent molecules of 2,4-bis(pivaloylamino)pyrimidine (M) with similar conformations, one water molecule and one-half n-hexane solvent molecule situated on an inversion center. In one independent M molecule, one of the two tert-butyl groups is rotationally disordered between two orientations in a 3:2 ratio. The n-hexane solvent molecule is disordered between two conformations in the same ratio. The water molecule bridges two independent M molecules via O-H...O, N-H...O and O-H...N hydrogen bonds into a 2M·H₂O unit, and these units are further linked by N-H...N hydrogen bonds into chains running in the [010] direction. Weak C-H...O interactions are observed between the adjacent chains.
Julkaisija
International Union of CrystallographyISSN Hae Julkaisufoorumista
1600-5368Asiasanat
Alkuperäislähde
http://dx.doi.org/10.1107/S160053681302713XJulkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/22815784
Metadata
Näytä kaikki kuvailutiedotKokoelmat
Lisenssi
Ellei muuten mainita, aineiston lisenssi on © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
Samankaltainen aineisto
Näytetään aineistoja, joilla on samankaltainen nimeke tai asiasanat.
-
Synthesis of a Novel Hydrazone of Thieno[2,3-d]pyrimidine Clubbed with Ninhydrin : X-ray Crystal Structure and Computational Investigations
Altowyan, Mezna Saleh; Haukka, Matti; Soliman, Saied M.; Barakat, Assem; Boraei, Ahmed T. A.; Sopaih, Manar (MDPI AG, 2023)The novel hydrazone-containing thieno[2,3-d]pyrimidine, namely, N′-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-2-(4-oxo-5,6,7,8-tetrahydrobenzo[4,5]thieno[2,3-d]pyrimidin-3(4H)-yl)acetohydrazide 4 was synthesized in a very ... -
Crystal structure of trans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
Lasri, J.; Eltayeb, N. E.; Haukka, Matti; Babgi, B. A. (International Union of Crystallography, 2017)The title complex, [PdCl2(C8H14N2O)2]2H2O, was obtained by N–O bond cleavage of the oxadiazoline rings of the trans-[dichlorido-bis(2,5,5-trimethyl- 5,6,7,7a-tetrahydropyrrolo[1,2-b][1,2,4]oxadiazole-N1 )]palladium(II) ... -
Crystal structure of 5-{3-[2,6-dimethyl- 4-(5-methyl-1,2,4-oxadiazol-3-yl)phenoxy]propyl}- N-(11-hydroxyundecyl)isoxazole-3-carboxamide hemihydrate
Salorinne, Kirsi; Lahtinen, Tanja (International Union of Crystallography, 2015)The title compound, C29H42N4O5·0.5H2O, comprises four structural units. A flexible propyloxy unit in a gauche conformation, with a -C(H2)-C(H2)-C(H2)-O- torsion angle of -64.32 (18)°, connects an isoxazole ring and an ... -
Preparation of potentially porous, chiral organometallic materials through spontaneous resolution of pincer palladium conformers
Johnson, Magnus T.; Dzolic, Zoran; Cetina, Mario; Lahtinen, Manu; Ahlquist, Mårten S. G.; Rissanen, Kari; Öhrström, Lars; Wendt, Ola F. (Royal Society of Chemistry, 2013)Understanding the mechanism by which advanced materials assemble is essential for the design of new materials with desired properties. Here, we report a method to form chiral, potentially porous materials through spontaneous ... -
Comparison of the polymorphs and solvates of two analogous fungicides—a case study of the applicability of a supramolecular synthon approach in crystal engineering
Nauha, Elisa; Ojala, Antti; Nissinen, Maija; Saxell, Heidi (Royal Society of Chemistry, 2011)The polymorphism and solvate formation of thiophanate-ethyl (TE), a fungicidal active, were investigated by solvent crystallization and compared to a close analogue, thiophanate-methyl (TM). Four polymorphs and seven ...
Ellei toisin mainittu, julkisesti saatavilla olevia JYX-metatietoja (poislukien tiivistelmät) saa vapaasti uudelleenkäyttää CC0-lisenssillä.