Crystal structure of trans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
Lasri, J., Eltayeb, N. E., Haukka, M., & Babgi, B. A. (2017). Crystal structure of trans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate. Acta Crystallographica Section E : Crystallographic Communications, E73 (4), 528-530. doi:10.1107/S2056989017003929
Date
2017Discipline
Epäorgaaninen ja analyyttinen kemiaCopyright
© the Authors, 2017. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
The title complex, [PdCl2(C8H14N2O)2]2H2O, was obtained by N–O bond
cleavage of the oxadiazoline rings of the trans-[dichlorido-bis(2,5,5-trimethyl-
5,6,7,7a-tetrahydropyrrolo[1,2-b][1,2,4]oxadiazole-N1
)]palladium(II) complex.
The palladium(II) atom exhibits an almost square-planar coordination provided
by two trans-arranged chloride anions and a nitrogen atom from each of the two
neutral organic ligands. In the crystal, N—HO, O—HO and O—HCl
hydrogen bonds link complex molecules into double layers parallel to the bc
plane.
Publisher
International Union of CrystallographyISSN Search the Publication Forum
2056-9890Metadata
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Except where otherwise noted, this item's license is described as © the Authors, 2017. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.