Crystal structure of trans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
Lasri, J., Eltayeb, N. E., Haukka, M., & Babgi, B. A. (2017). Crystal structure of trans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate. Acta Crystallographica Section E : Crystallographic Communications, E73(4), 528-530. https://doi.org/10.1107/S2056989017003929
Julkaistu sarjassa
Acta Crystallographica Section E : Crystallographic CommunicationsPäivämäärä
2017Tekijänoikeudet
© the Authors, 2017. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
The title complex, [PdCl2(C8H14N2O)2]2H2O, was obtained by N–O bond
cleavage of the oxadiazoline rings of the trans-[dichlorido-bis(2,5,5-trimethyl-
5,6,7,7a-tetrahydropyrrolo[1,2-b][1,2,4]oxadiazole-N1
)]palladium(II) complex.
The palladium(II) atom exhibits an almost square-planar coordination provided
by two trans-arranged chloride anions and a nitrogen atom from each of the two
neutral organic ligands. In the crystal, N—HO, O—HO and O—HCl
hydrogen bonds link complex molecules into double layers parallel to the bc
plane.
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International Union of CrystallographyISSN Hae Julkaisufoorumista
2056-9890Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/26975555
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