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dc.contributor.authorPan, Shulei
dc.contributor.authorMulks, Florian
dc.contributor.authorWu, Peng
dc.contributor.authorRissanen, Kari
dc.contributor.authorBolm, Carsten
dc.date.accessioned2024-02-21T07:16:57Z
dc.date.available2024-02-21T07:16:57Z
dc.date.issued2024
dc.identifier.citationPan, S., Mulks, F., Wu, P., Rissanen, K., & Bolm, C. (2024). Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones. <i>Angewandte Chemie</i>, <i>63</i>(5), Article e202316702. <a href="https://doi.org/10.1002/anie.202316702" target="_blank">https://doi.org/10.1002/anie.202316702</a>
dc.identifier.otherCONVID_194896868
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/93512
dc.description.abstractA mechanochemical synthesis of sulfonimidamides by iron(II)-catalyzed exogenous ligand-free N-acyl nitrene transfer to sulfinamides is reported. The one-step method tolerates a wide range of sulfinamides with various substituents under solvent-free ambient conditions. Compared to its solution-phase counterpart, this mechanochemical approach shows better conversion and chemoselectivity. Mechanistic investigations by ESI-MS revealed the generation of crucial nitrene iron intermediates.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsCC BY 4.0
dc.titleMechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202402211979
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.relation.issn1433-7851
dc.relation.numberinseries5
dc.relation.volume63
dc.type.versionpublishedVersion
dc.rights.copyright© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
dc.rights.accesslevelopenAccessfi
dc.subject.ysotyppiyhdisteet
dc.subject.ysokemiallinen synteesi
dc.subject.ysorikkiyhdisteet
dc.subject.ysokatalyysi
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p640
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p5731
jyx.subject.urihttp://www.yso.fi/onto/yso/p8704
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1002/anie.202316702
jyx.fundinginformationS.P. and P.W. thank to the China Scholarship Council (CSC) for predoctoral stipends. F.F.M. is grateful to the Fonds der Chemischen Industrie for a Liebig Fellowship (Li 210/01).
dc.type.okmA1


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