Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones
| dc.contributor.author | Pan, Shulei | |
| dc.contributor.author | Mulks, Florian | |
| dc.contributor.author | Wu, Peng | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Bolm, Carsten | |
| dc.date.accessioned | 2024-02-21T07:16:57Z | |
| dc.date.available | 2024-02-21T07:16:57Z | |
| dc.date.issued | 2024 | |
| dc.identifier.citation | Pan, S., Mulks, F., Wu, P., Rissanen, K., & Bolm, C. (2024). Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones. <i>Angewandte Chemie</i>, <i>63</i>(5), Article e202316702. <a href="https://doi.org/10.1002/anie.202316702" target="_blank">https://doi.org/10.1002/anie.202316702</a> | |
| dc.identifier.other | CONVID_194896868 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/93512 | |
| dc.description.abstract | A mechanochemical synthesis of sulfonimidamides by iron(II)-catalyzed exogenous ligand-free N-acyl nitrene transfer to sulfinamides is reported. The one-step method tolerates a wide range of sulfinamides with various substituents under solvent-free ambient conditions. Compared to its solution-phase counterpart, this mechanochemical approach shows better conversion and chemoselectivity. Mechanistic investigations by ESI-MS revealed the generation of crucial nitrene iron intermediates. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.relation.ispartofseries | Angewandte Chemie | |
| dc.rights | CC BY 4.0 | |
| dc.title | Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202402211979 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.relation.issn | 1433-7851 | |
| dc.relation.numberinseries | 5 | |
| dc.relation.volume | 63 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.subject.yso | typpiyhdisteet | |
| dc.subject.yso | kemiallinen synteesi | |
| dc.subject.yso | rikkiyhdisteet | |
| dc.subject.yso | katalyysi | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p640 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8468 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p5731 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8704 | |
| dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
| dc.relation.doi | 10.1002/anie.202316702 | |
| jyx.fundinginformation | S.P. and P.W. thank to the China Scholarship Council (CSC) for predoctoral stipends. F.F.M. is grateful to the Fonds der Chemischen Industrie for a Liebig Fellowship (Li 210/01). | |
| dc.type.okm | A1 |
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