Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones
Pan, S., Mulks, F., Wu, P., Rissanen, K., & Bolm, C. (2024). Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones. Angewandte Chemie, 63(5), Article e202316702. https://doi.org/10.1002/anie.202316702
Julkaistu sarjassa
Angewandte ChemiePäivämäärä
2024Tekijänoikeudet
© 2023 The Authors. Angewandte Chemie International Edition
published by Wiley-VCH GmbH.
A mechanochemical synthesis of sulfonimidamides by iron(II)-catalyzed exogenous ligand-free N-acyl nitrene transfer to sulfinamides is reported. The one-step method tolerates a wide range of sulfinamides with various substituents under solvent-free ambient conditions. Compared to its solution-phase counterpart, this mechanochemical approach shows better conversion and chemoselectivity. Mechanistic investigations by ESI-MS revealed the generation of crucial nitrene iron intermediates.
Julkaisija
Wiley-VCH VerlagISSN Hae Julkaisufoorumista
1433-7851Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/194896868
Metadata
Näytä kaikki kuvailutiedotKokoelmat
Lisätietoja rahoituksesta
S.P. and P.W. thank to the China Scholarship Council (CSC) for predoctoral stipends. F.F.M. is grateful to the Fonds der Chemischen Industrie for a Liebig Fellowship (Li 210/01).Lisenssi
Ellei muuten mainita, aineiston lisenssi on CC BY 4.0