dc.contributor.author | Kumar, Parveen | |
dc.contributor.author | Komulainen, Joonas | |
dc.contributor.author | Frontera, Antonio | |
dc.contributor.author | Ward, Jas S. | |
dc.contributor.author | Schalley, Christoph | |
dc.contributor.author | Rissanen, Kari | |
dc.contributor.author | Puttreddy, Rakesh | |
dc.date.accessioned | 2024-02-14T13:01:48Z | |
dc.date.available | 2024-02-14T13:01:48Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | Kumar, P., Komulainen, J., Frontera, A., Ward, J. S., Schalley, C., Rissanen, K., & Puttreddy, R. (2023). Linear bis‐Coordinate Silver(I) and Iodine(I) Complexes with R3R2R1N Tertiary Amines. <i>Chemistry : A European Journal</i>, <i>29</i>(69), Article e202302162. <a href="https://doi.org/10.1002/chem.202302162" target="_blank">https://doi.org/10.1002/chem.202302162</a> | |
dc.identifier.other | CONVID_184767134 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/93400 | |
dc.description.abstract | Homoleptic [L–I–L]⁺ iodine(I) complexes (where L is a R3R2R1N tertiary amine) were synthesized via the [L–Ag–L]⁺ → [L–I–L]⁺ cation exchange reaction. In solution, the amines form [R3R2R1N-Ag-NR1R2R3]⁺ silver(I) complexes, which crystallize out from solution as the meso-[L–Ag–L]+complexes, as characterized by X-ray crystallography. The subsequent [L–I–L]⁺ iodine(I) analogues were extremely reactive and could not be isolated in the solid state. Density Functional Theory (DFT) calculations were performed to study the Ag⁺–N and I⁺–N interaction energies in silver(I) and iodine(I) complexes, with the former ranging from -80 to -100 kJmol-1 and latter from -260 to -279 kJmol-1. The X-ray crystal structures revealed Ag+···Cπ and Ag+···H–C short contacts between the silver(I) cation and flexible N-alkyl/N-aryl groups, which are the first of their kind in such precursor complexes. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | Wiley-VCH Verlag | |
dc.relation.ispartofseries | Chemistry : A European Journal | |
dc.rights | CC BY 4.0 | |
dc.subject.other | halogen bond | |
dc.subject.other | meso | |
dc.subject.other | tertiary amines | |
dc.subject.other | X-ray structure | |
dc.subject.other | coordination bond | |
dc.title | Linear bis‐Coordinate Silver(I) and Iodine(I) Complexes with R3R2R1N Tertiary Amines | |
dc.type | research article | |
dc.identifier.urn | URN:NBN:fi:jyu-202402141878 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Soveltavan kemian yksikkö | fi |
dc.contributor.oppiaine | Orgaaninen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | The Unit of Applied Chemistry | en |
dc.contributor.oppiaine | Organic Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.relation.issn | 0947-6539 | |
dc.relation.numberinseries | 69 | |
dc.relation.volume | 29 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © 2023 the Authors | |
dc.rights.accesslevel | openAccess | fi |
dc.type.publication | article | |
dc.relation.grantnumber | 351121 | |
dc.relation.grantnumber | 298817 | |
dc.subject.yso | jodi | |
dc.subject.yso | kemialliset sidokset | |
dc.subject.yso | halogeenit | |
dc.subject.yso | kompleksiyhdisteet | |
dc.subject.yso | amiinit | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p18902 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p10130 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p4164 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p9219 | |
dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
dc.relation.doi | 10.1002/chem.202302162 | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
jyx.fundingprogram | Academy Project, AoF | en |
jyx.fundingprogram | Postdoctoral Researcher, AoF | en |
jyx.fundingprogram | Akatemiahanke, SA | fi |
jyx.fundingprogram | Tutkijatohtori, SA | fi |
jyx.fundinginformation | The authors gratefully acknowledge financial support from the Academy of Finland (RP grant no. 29881, K.R. 351121) and University of Jyväskylä. | |
dc.type.okm | A1 | |